[5,10,15-tris(4-tert-butylphenyl)-2:3,7:8,12:13,17:18-tetrabenzo-2'',3'',7'',8'',12'',13'',17'',18''-octakis(carboxymethyl)corrolato]-gallium(pyridine) | 1426913-18-9

• 英文名称: [5,10,15-tris(4-tert-butylphenyl)-2:3,7:8,12:13,17:18-tetrabenzo-2'',3'',7'',8'',12'',13'',17'',18''-octakis(carboxymethyl)corrolato]-gallium(pyridine)
• 英文别名: [TBCorr]Ga(py)
• CAS: 1426913-18-9
• 化学式: C₈₆H₇₆GaN₅O₁₆
• 分子量: 1505.3
• InChiKey: LZHAFBHLOSUXDT-VPGDKSHCSA-K

反应信息

• 作为产物：
  描述：

  吡啶 、 5,10,15-tris(4-tert-butylphenyl)-2:3,7:8,12:13,17:18-tetrabenzo-2'',3'',7'',8'',12'',13'',17'',18''-octakis(carboxymethyl)corrole 、 gallium(III) acetylacetonate 反应 2.0h， 以66%的产率得到[5,10,15-tris(4-tert-butylphenyl)-2:3,7:8,12:13,17:18-tetrabenzo-2'',3'',7'',8'',12'',13'',17'',18''-octakis(carboxymethyl)corrolato]-gallium(pyridine)
  参考文献：
  名称：

  Aluminum, Gallium, Germanium, Copper, and Phosphorus Complexes of meso-Triaryltetrabenzocorrole

  摘要：

  5,10,15-Triaryltetrabenzocorrole complexes of aluminum, gallium, germanium, and phosphorus were synthesized by coordination of these metal ions in the preformed triaryltetrabenzocorrole macrocycle, opening a way to the investigation of different metal complexes. The UV-vis spectra of these derivatives exhibit a red shift and broadening of all absorption bands because of the pi-extended aromatic system and distortion of the molecular framework. The electrochemical and photophysical behaviors of the free base and the metal complexes of meso-triaryltetrabenzocorrole were investigated and characterized.

  DOI：

  10.1021/ic400162y