cyclopenta-1,3-diene;diiodocobalt(1+);methyl(diphenyl)phosphane;triphenylphosphane | 486407-32-3

• 英文名称: cyclopenta-1,3-diene;diiodocobalt(1+);methyl(diphenyl)phosphane;triphenylphosphane
• CAS: 486407-32-3
• 化学式: C₃₆H₃₃CoIP₂*I
• 分子量: 840.408
• InChiKey: YRXKXILSSASMOC-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  9.37
• 重原子数：
  41
• 可旋转键数：
  5
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.03
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  cyclopenta-1,3-diene;diiodocobalt(1+);methyl(diphenyl)phosphane;triphenylphosphane 、 四苯硼钠 以 二氯甲烷 为溶剂， 以79%的产率得到cyclopenta-1,3-diene;iodocobalt(2+);methyl(diphenyl)phosphane;tetraphenylboranuide;triphenylphosphane
  参考文献：
  名称：

  摘要：

  The ionic complexes [C5H5Co(L)(Ph2PMe)I](+) [I](-) (L = Ph3P and Ph2PMe) were prepared by the reactions of cyclopentadienyl(triphenylphosphine)cobalt and cyclopentadienyl(methyldiphenylphosphine)cobalt diiodides with methyldiphenylphosphine. The treatment of these complexes with sodium tetraphenylborate results in the formation of [C5H5Co(L)(Ph2PMe)I](+)[BPh4](-) compounds.

  DOI：

  10.1023/a:1019543831887
• 作为产物：
  描述：

  cyclopentadienyl(triphenylphosphine)cobalt diiodide 、 二苯基甲氧基膦 以 二氯甲烷 为溶剂， 以76%的产率得到cyclopenta-1,3-diene;diiodocobalt(1+);methyl(diphenyl)phosphane;triphenylphosphane
  参考文献：
  名称：

  摘要：

  The ionic complexes [C5H5Co(L)(Ph2PMe)I](+) [I](-) (L = Ph3P and Ph2PMe) were prepared by the reactions of cyclopentadienyl(triphenylphosphine)cobalt and cyclopentadienyl(methyldiphenylphosphine)cobalt diiodides with methyldiphenylphosphine. The treatment of these complexes with sodium tetraphenylborate results in the formation of [C5H5Co(L)(Ph2PMe)I](+)[BPh4](-) compounds.

  DOI：

  10.1023/a:1019543831887