[Pd(Ar(F)2nacnac)(μ-Cl)]2 | 1356928-44-3

• 英文名称: [Pd(Ar(F)2nacnac)(μ-Cl)]2
• 英文别名: [Pd((3,5-bis(trifluoromethyl)phenyl)2nacnac)(μ-Cl)]2
• CAS: 1356928-44-3
• 化学式: C₄₂H₂₆Cl₂F₂₄N₄Pd₂
• 分子量: 1326.4
• InChiKey: AOWFLDHJUGZKIX-MPGWHFEQSA-L

反应信息

• 作为反应物：
  描述：

  吡啶 、 [Pd(Ar(F)2nacnac)(μ-Cl)]2 以 二氯甲烷 为溶剂， 以88%的产率得到[Pd(((Ar(F))2nacnac)Cl(Py)]
  参考文献：
  名称：

  Palladium β-diiminate chemistry: Reactivity towards monodentate ligands and arylboronic acids

  摘要：

  Here we report the synthesis and characterization of a series of palladium beta-diiminate complexes. Chloro-bridged dimers [Pd(Ar(2)nacnac)(mu-Cl)](2) (where [Ar(2)nacnac] is [(ArNC(CH3))(2)CH] with Ar being aryl substituents) can serve as versatile starting materials, and can be cleaved by neutral monodentate ligands (L) to form mononuclear complexes [Pd(Ar(2)nacnac)(L)Cl], or engage in unusual transmetallation reactions with boronic acids to form tetrapallada-macrocycles. The reactivity of the tetrapallada-macrocyclic complexes towards L-type ligands, as well as the reactivity of Pd(Ar(2)nacnac)(L)Cl] complexes towards boronic acids was also also explored. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.09.044
• 作为产物：
  描述：

  sodium tetrachloropalladate(II) 、 (Ar(F))2nacnacH 在 KO(tBu) 作用下， 以 甲醇 为溶剂， 以25%的产率得到[Pd(Ar(F)2nacnac)(μ-Cl)]2
  参考文献：
  名称：

  Palladium β-diiminate chemistry: Reactivity towards monodentate ligands and arylboronic acids

  摘要：

  Here we report the synthesis and characterization of a series of palladium beta-diiminate complexes. Chloro-bridged dimers [Pd(Ar(2)nacnac)(mu-Cl)](2) (where [Ar(2)nacnac] is [(ArNC(CH3))(2)CH] with Ar being aryl substituents) can serve as versatile starting materials, and can be cleaved by neutral monodentate ligands (L) to form mononuclear complexes [Pd(Ar(2)nacnac)(L)Cl], or engage in unusual transmetallation reactions with boronic acids to form tetrapallada-macrocycles. The reactivity of the tetrapallada-macrocyclic complexes towards L-type ligands, as well as the reactivity of Pd(Ar(2)nacnac)(L)Cl] complexes towards boronic acids was also also explored. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.09.044