| 183375-57-7

• CAS: 183375-57-7
• 化学式: CF₃O₃S*C₄₅H₄₁AgAs₂Au
• 分子量: 1185.57
• InChiKey: FJRRJTNKIVZPOH-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  、 三苯胂 以 二氯甲烷 为溶剂， 以99%的产率得到
  参考文献：
  名称：

  Trinuclear Au₂Ag and Au₂Cu Complexes with Mesityl Bridging Ligands. X-ray Structure of the Chain Polymer [{Au(μ-mes)AsPh₃}₂Ag](ClO₄)

  摘要：

  The reaction of the complex [Au(mes)L] (mes = mesityl, L = PPh(3), AsPh(3)) with Ag(OSO2CF3), Ag(OClO3), or [Cu(CNMe)(4)]PF6, in molar ratio 2:1, affords trinuclear derivatives [{Au-mu-mes)L}(2)M]A [M = Ag, L = PPh(3), A = SO3CF3- (1); L = AsPh(3), A = ClO4- (2a), SO3CF3-(2b); M = Cu, A = PF6- L = PPh(3) (3), AsPh(3) (4)]. Complexes 1 and 2 react further with various ligands in a 1:1 molar ratio to give the dinuclear compounds [AuAg(mu-mes)(PPh(3))L]SO3CF3 (L = PPh(3), tetrahydrothiophene, 2,2'-bipyridine, or SPPh(3)) or [AuAg(mu-mes)(AsPh(3))L]A (L = AsPh(3), A = SO3CF3-; L = 1/2 Ph(2)AsCH(2)AsPh(2), A = ClO4-). The structure of [{Au(mu-mes)AsPh(3)}Ag-2](ClO4) (2a) has been determined by a single-crystal X-ray diffraction study, which shows an Au-Ag distance of 2.7758(8) Angstrom; the trinuclear species are connected by short Au Au contacts of 3.132 Angstrom to form a chain polymer.

  DOI：

  10.1021/om9602062