| 556104-35-9

• CAS: 556104-35-9
• 化学式: C₆₀H₄₄BF₁₅FeN₂Zr
• 分子量: 1235.88
• InChiKey: OHXMHNJTZSTWPM-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  、 三(五氟苯基)硼烷 以 氘代苯 为溶剂， 生成
  参考文献：
  名称：

  Zirconium complexes incorporating diaryldiamidoferrocene ligands: generation of cationic derivatives and polymerization activity towards ethylene and 1-hexene

  摘要：

  Palladium-catalyzed coupling of ArX (ArX = MesBr, 2,6-dichloroiodobenzene and 9-bromonaphtalene) with 1,1'-diaminoferrocene afforded a series of substituted diamide ligands Fc(NHAr)(2) (1). A Zr-dibenzyl complex 2 of the mesityl-substituted ligand was synthesized using ZrBn4, and its ability to act as precatalyst for olefin polymerization was investigated. Abstraction of one benzyl group using B(C6F5)(3) resulted in the zwitterionic species [LZrBn][BnB(C6F5)(3)] (3), which reacted slowly (approximately 30 min) with ethylene to afford the monoinsertion product [LZrCH2CH2CH2Ph][BnB(C6F5)(3)]. Further insertions of ethylene were slower and led, after 2 h, to the di- and tri-insertion products. Use of [Ph3C][B(C6F5)(4)] as an activator resulted in a competent 1-hexene polymerization catalyst affording high molecular weight poly-l-hexene with a PDI of 1.3-1.4. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(02)01300-2