PdCl2Fe[η-C5H4NC(H)Ph-N]2 | 667420-83-9

• 英文名称: PdCl2Fe[η-C5H4NC(H)Ph-N]2
• CAS: 667420-83-9
• 化学式: C₂₄H₂₀Cl₂FeN₂Pd
• 分子量: 569.609
• InChiKey: OIRKYNXHBLUYGT-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  双(乙腈)氯化钯(II) 、 N,N'-bis(benzaldimine)ferroceneamine 以 甲醇 为溶剂， 以84%的产率得到PdCl2Fe[η-C5H4NC(H)Ph-N]2
  参考文献：
  名称：

  Suzuki cross-coupling in aqueous media catalyzed by a 1,1′-N-substituted ferrocenediyl Pd(II) complex

  摘要：

  Reaction of PdCl2(MeCN)(2) with Fe[eta-C5H4NC(H)Ph-N](2) (1) at MeOH at r.t. gives air-stable PdCl2Fe[eta-C5H4NC(H)Ph-N](2) (2; yield 84%). X-ray single-crystal diffraction analyses show that 2 is a Pd(II) square planar complex with N,N' chelation of the ferrocenediyl ligand, without Fe-Pd bond. It effectively catalyzes Suzuki cross-coupling reactions of aryl iodides and bromides with aryl boronic acids in aqueous media under non-homogeneous conditions in which the products can be easily isolated. The reaction conditions including choice of base, catalytic load and catalyst recoverability have been investigated and reported. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2003.09.028