| 1296203-61-6

• CAS: 1296203-61-6
• 化学式: C₄₂H₅₅ClN₆Si₂
• 分子量: 735.563
• InChiKey: BDHQOKXEFFDNIZ-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  N,N′-di-tertbutyl(phenylamidinato)chlorosilylene 、 偶氮苯 以 甲苯 为溶剂， 反应 12.0h， 生成
  参考文献：
  名称：

  Formation of a Unsymmetrical Ring System via C–H Bond Activation of Diazobenzene by Stable N-Heterocyclic Chlorosilylene (PhC(NtBu)₂SiCl)

  摘要：

  The reaction of N-heterocyclic chlorosilylene (1; LSiCl, L = PhC(NtBu)(2)) with diazobenzene is described, which afforded the unsymmetrical polycyclic product 2 via chlorosilylene mediated aromatic C-H bond activation. The reaction proceeds without the cleavage of the N-N bond of diazobenzene. Polycycle 2 was fully characterized by single-crystal X-ray diffraction analysis, multinuclear NMR spectroscopy, EI-MS spectrometry, and elemental analysis.

  DOI：

  10.1021/om200207v