Pt(P(C6H11)3)2(η(2)-C60) | 193681-06-0

• 英文名称: Pt(P(C6H11)3)2(η(2)-C60)
• CAS: 193681-06-0
• 化学式: C₉₆H₆₆P₂Pt
• 分子量: 1476.61
• InChiKey: NNBBANRLZXHIIB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  trans-dihydridobis(tricyclohexylphosphine)platinum 、 足球烯 以 甲苯 为溶剂， 以72%的产率得到Pt(P(C6H11)3)2(η(2)-C60)
  参考文献：
  名称：

  Reaction of trans-[Pt(H)2(PCy3)2] with C60 reductive elimination of H2 and formation of [Pt(PCy3)2(η2-C60)]

  摘要：

  Reaction of trans-[Pt(H)(2)(PCy3)(2)], 1, with [60]fullerene at room temperature affords [Pt(PCy3)(2)(eta(2)-C-60)], 2, in nearly quantitative yield. The most probable reaction pattern is the insertion of a fullerene 6,6 junction onto a Pt-H bond yielding an eta(1) alkyl derivative which, after hydrogen extrusion, gives 2. On the other hand, addition of 1 to different electron-deficient olefins, such as dimethyl maleate and fumarate, furnishes mixtures of both eta(1) metal-alkyl and eta(2) metal-olefin derivatives. If tetrachloroethylene is used as 2 pi component, trans-[PtCl(H)(PCy3)(2)] forms exclusively. (C) 1997 Elsevier Science S.A.

  DOI：

  10.1016/s0022-328x(97)00081-8