trans-bis-[1,2-bis(diphenylphosphino)ethane]-fluoro-(diazopropano)-molybdenum tetraphenylborate | 663910-08-5

• 英文名称: trans-bis-[1,2-bis(diphenylphosphino)ethane]-fluoro-(diazopropano)-molybdenum tetraphenylborate
• CAS: 663910-08-5
• 化学式: C₂₄H₂₀B*C₅₅H₅₄FMoN₂P₄
• 分子量: 1301.11
• InChiKey: ULSJFUUOLQOQJR-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  trans-[MoF(NNH2)((C6H5)2PC2H4P(C6H5)2)2][B(C6H5)4] 、 四苯硼钠 、 丙醛 以 二氯甲烷 为溶剂， 生成 trans-bis-[1,2-bis(diphenylphosphino)ethane]-fluoro-(diazopropano)-molybdenum tetraphenylborate
  参考文献：
  名称：

  Immobilization of Mo(IV) complex in hybrid matrix obtained via sol–gel technique

  摘要：

  A molybdenum(IV) complex, trans-bis-[1,2-bis(diphenylphosphino)ethane]-fluoro-(diazopropano)-molybdenum tetraphenylborate, [MoF(DIAZO)(dppe)(2)][BPh4] was prepared and immobilized in a hybrid matrix synthesized by the sol-gel process. The host matrix, designated as U(500), is an organic-inorganic network material, classed as ureasil, that combines a reticulated siliceous backbone linked by short polyether-based segments. Urea bridges make the link between these two components, and the polymerization of silicate substituted terminal groups generates the inorganic network. The free Mo(IV) complex and all new materials were characterized by spectroscopic techniques (FT-IR and UV-Vis) and thermal analysis (DSC). The ionic conductivity of the resulting material was also studied. The results indicate that immobilized Mo(W) complex has kept its solid-state structure, although there is evidence of inter-molecular interactions between the Mo(IV) complex and some groups/atoms of the hybrid host matrix. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/s0925-8388(03)00348-7