diphenylthallium(III) methylxanthate | 616900-07-3

• 英文名称: diphenylthallium(III) methylxanthate
• 英文别名: Ph2Tl(S2COMe)
• CAS: 616900-07-3
• 化学式: C₁₄H₁₃OS₂Tl
• 分子量: 465.772
• InChiKey: CHKQPUZILILLOO-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  sodium methyl xanthate 、 溴(二苯基)铊烷 以 乙醇 、 二氯甲烷 为溶剂， 以51%的产率得到diphenylthallium(III) methylxanthate
  参考文献：
  名称：

  Supramolecular self-assembly of Ph2Tl(S2COMe) based on a rare coordination mode of the xanthate ligand and thallium⋯π-phenyl interactions

  摘要：

  Diphenylthallium(Ell) xanthates, Ph2TI(S2COR), R = Me, Et, iso-Pr, Bz, have been prepared from Ph2TlBr and KS2COR, and the crystal structure of Ph2Tl(S2COMe) has been determined by single crystal X-ray diffraction. The compound displays a supramolecular structure consisting of Ph(2)T1(S2COMe) tectons, self-assembled through intermolecular T1 (. . .) S and T1... 0 secondary bonds and T1(. . .)pi-phenyl interactions. (C) 2003 Published by Elsevier B.V.

  DOI：

  10.1016/s0022-2860(03)00344-2