| 111496-05-0

• CAS: 111496-05-0
• 化学式: C₄H₁₂Cl₂Mo₄O₁₄*2C₁₆H₃₆N
• 分子量: 1223.73
• InChiKey: CJZDMZKAALZENG-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 丙酮肟 以 甲醇 为溶剂， 生成
  参考文献：
  名称：

  Reactivity of acetone oxime towards oxomolybdenum(VI) complexes. Part 1. Syntheses and crystal structures of tetranuclear molybdenum(VI) complexes

  摘要：

  Reaction of acetone oxime with [NBu(n)4]4[alpha-Mo8O26] in refluxing methanol yielded [NBu(n)4]2[Mo4O12(Me2CNO)2] 1 while that with [MoO2(acac)2] (acac = acetylacetonate) at room temperature resulted in the formation of [Mo4O10(OMe)4(Me2CNHO)2] 2. The crystal structures of 1 and 2 have been determined [1, space group P1BAR, a = 9.009(1), b = 17.860(1), c = 16.769(1) angstrom, alpha = 91.624(5), beta = 101.1 58(7), gamma = 91.983(7)-degrees, R = 0.037 for 7429 reflections with I > 3sigma(I); 2, space group P2(1)/c, a = 9.437(1), b = 8.827(1), c = 13.727(3) angstrom, beta = 92.15(1)-degrees, R = 0.029 for 2821 reflections with I > 3sigma(I)]. The anion of 1 displays a cyclic (MoO2)4(mu-O)4 ring while 2 displays a Mo(VI)4(mu3-OMe)2 central core. The mu4-kappa2N:kappa2O co-ordination mode exhibited by the acetone oximate in 1 is unprecedented for such a ligand, so is the end-on co-ordination mode of zwitterionic acetone oxime in 2. The reactivity of 1 and 2 respectively towards hydrochloric acid and tetrabutylammonium hydroxide was studied.

  DOI：

  10.1039/dt9940000819
• 作为产物：
  描述：

  在 HCl 作用下， 以 甲醇 为溶剂， 生成
  参考文献：
  名称：

  Reactivity of acetone oxime towards oxomolybdenum(VI) complexes. Part 1. Syntheses and crystal structures of tetranuclear molybdenum(VI) complexes

  摘要：

  Reaction of acetone oxime with [NBu(n)4]4[alpha-Mo8O26] in refluxing methanol yielded [NBu(n)4]2[Mo4O12(Me2CNO)2] 1 while that with [MoO2(acac)2] (acac = acetylacetonate) at room temperature resulted in the formation of [Mo4O10(OMe)4(Me2CNHO)2] 2. The crystal structures of 1 and 2 have been determined [1, space group P1BAR, a = 9.009(1), b = 17.860(1), c = 16.769(1) angstrom, alpha = 91.624(5), beta = 101.1 58(7), gamma = 91.983(7)-degrees, R = 0.037 for 7429 reflections with I > 3sigma(I); 2, space group P2(1)/c, a = 9.437(1), b = 8.827(1), c = 13.727(3) angstrom, beta = 92.15(1)-degrees, R = 0.029 for 2821 reflections with I > 3sigma(I)]. The anion of 1 displays a cyclic (MoO2)4(mu-O)4 ring while 2 displays a Mo(VI)4(mu3-OMe)2 central core. The mu4-kappa2N:kappa2O co-ordination mode exhibited by the acetone oximate in 1 is unprecedented for such a ligand, so is the end-on co-ordination mode of zwitterionic acetone oxime in 2. The reactivity of 1 and 2 respectively towards hydrochloric acid and tetrabutylammonium hydroxide was studied.

  DOI：

  10.1039/dt9940000819

文献信息

• Kang, Hyunkyu; Liu, Shuncheng; Shaikh, Shahid N., Inorganic Chemistry, 1989, vol. 28, # 5, p. 920 - 933
  作者：Kang, Hyunkyu、Liu, Shuncheng、Shaikh, Shahid N.、Nicholson, Terrence、Zubieta, Jon

  DOI：——

  日期：——
• Liu, Shuncheng; Shaikh, Shahid N.; Zubieta, Jon, Inorganic Chemistry, 1987, vol. 26, # 26, p. 4303 - 4305
  作者：Liu, Shuncheng、Shaikh, Shahid N.、Zubieta, Jon

  DOI：——

  日期：——