(η5-cyclopentadienyl)(η6-diphenylmethane)iron(II)tetraphenylborate | 55318-85-9

• 英文名称: (η5-cyclopentadienyl)(η6-diphenylmethane)iron(II)tetraphenylborate
• CAS: 55318-85-9
• 化学式: C₁₈H₁₇Fe*C₂₄H₂₀B
• 分子量: 608.414
• InChiKey: DCSCQIJVFHMJJV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  盐酸 、 四苯基硼酸钠盐 、 (η5-cyclopentadienyl)[η6-diphenyl(trifluoroacetoxymercurio)methane]iron(II) hexafluorophosphate(V) 以 盐酸 为溶剂， 生成 (η5-cyclopentadienyl)(η6-diphenylmethane)iron(II)tetraphenylborate
  参考文献：
  名称：

  Reaction of Mercury(II) Trifluoroacetate with Deprotonated ( ⁶-Toluene)-, ( ⁶-Diphenylmethane)-, and ( ⁶-Triphenylmethane)( ⁵-cyclopentadienyl)iron(II) Complexes. Mercuration of Some Cationic (Arene)(cyclopentadienyl)iron(II) Complexes

  摘要：

  Treatment with mercury(II) trifluoroacetate of deprotonated (eta(6)-toluene)- and (eta(6)-diphenylmethane)(eta(5)-cyclopentadienyl)iron(II) complexes gave mono-, di-, and trisubstituted [from (eta(6)-toluene)(eta(5)-cyclopentadienyl)iron(II) cation] mercury-containing salts. The reaction of mercury(II) trifluoroacetate with deprotonated (eta(6)-triphenylmethane)(eta(5)-cyclopentadienyl)iron(II) afforded only the corresponding symmetric mercury derivative. The same product was obtained by direct mercuration with mercury(II) trifluoroacetate of (eta(6)-triphenylmethane)(eta(5)-cyclopentadienyl)iron(II) on heating the reactants in boiling unhydrous ethanol. Reactions of the resulting mercury-containing compounds with acids, symmetrizing bases, and acylating agents were studied.

  DOI：

  10.1023/b:rugc.0000016024.46430.89