| 145088-69-3

• CAS: 145088-69-3
• 化学式: BF₄*C₃₁H₂₆MnO₄P₂
• 分子量: 666.235
• InChiKey: MKNQNZQTLBMNRM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  在 NaN₃ 、 C₆H₆ 作用下， 以 甲醇 为溶剂， 以86-90的产率得到
  参考文献：
  名称：

  The synthesis of alkoxycarbonyl, carbamoyl and isocyanato complexes, fac-M(CO)3(P-P)Z [M = Mn, Re; P-P = dppe, dppp; Z = C(O)OMe, C(O)OEt, C(O)NHPrn, NCO]. The single crystal structures of fac-Mn(CO)3(dppp)C(O)OEt and fac-Mn(CO)3(dppe)NCO

  摘要：

  The title compounds were prepared by the reaction of the cationic complex [M(CO)4(P-P)]+[BF4]- With the appropriate nucleophiles leading to fac-M(CO)3(P-P)Z [M = Mn, Re; P-P = dppe, dppp; Z = C(O)OMe, C(O)OEt, C(O)NHPrn, NCO] complexes. The X-ray structures of fac-Mn(CO)3(dppp)C(O)OEt and fac-Mn(CO)3(dppe)NCO are also reported.

  DOI：

  10.1016/s0277-5387(00)83162-9
• 作为产物：
  描述：

  fac-Mn(CO)3(1,3-bis(diphenylphosphino)propane)Br 、 silver tetrafluoroborate 在 CO 作用下， 以 二氯甲烷 为溶剂， 以89-93的产率得到
  参考文献：
  名称：

  The synthesis of alkoxycarbonyl, carbamoyl and isocyanato complexes, fac-M(CO)3(P-P)Z [M = Mn, Re; P-P = dppe, dppp; Z = C(O)OMe, C(O)OEt, C(O)NHPrn, NCO]. The single crystal structures of fac-Mn(CO)3(dppp)C(O)OEt and fac-Mn(CO)3(dppe)NCO

  摘要：

  The title compounds were prepared by the reaction of the cationic complex [M(CO)4(P-P)]+[BF4]- With the appropriate nucleophiles leading to fac-M(CO)3(P-P)Z [M = Mn, Re; P-P = dppe, dppp; Z = C(O)OMe, C(O)OEt, C(O)NHPrn, NCO] complexes. The X-ray structures of fac-Mn(CO)3(dppp)C(O)OEt and fac-Mn(CO)3(dppe)NCO are also reported.

  DOI：

  10.1016/s0277-5387(00)83162-9

文献信息

• The synthesis and reactions of Mn and Re formyl complexes, fac-(PP)M(CO)3CHO. The X-ray structure of fac-(dppp)Mn(CO)3CH2OCH3
  作者：Santosh K. Mandal、Jeanette A. Krause、Milton Orchin

  DOI：10.1016/0022-328x(94)88015-8

  日期：1994.3

  Treatment of the salts fac-[(P-P)M(CO)4][BF4] (M = Mn, Re; P-P = dppe, dppp) with NaBH4 gives the corresponding formyl complexes, fac-(P-P)M(CO)3CHO in excellent yield. Solutions of these formyls undergo spontaneous loss of CO to give the corresponding hydrides, fac-(P-P)M(CO)3H. On treatment with methyl triflate or protic acids the formyls undergo expected disproportionation reactions; the X-ray crystal structure determination of one of the products, fac-(dppp)Mn(CO)3CH2OCH3, is reported.