lanthanum trialuminide | 12043-35-5

• 英文名称: lanthanum trialuminide
• 英文别名: Aluminium--lanthanum (3/1)；alumane;lanthanum
• CAS: 12043-35-5
• 化学式: Al₃La
• 分子量: 219.85
• InChiKey: KPMAQWRYGGVOQJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -3.55
• 重原子数：
  4
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  三氢化镧 、 氢化铝 以 neat (no solvent, solid phase) 为溶剂， 生成 lanthanum trialuminide
  参考文献：
  名称：

  高压下合成的 RA13 化合物中 111Cd 原子核超精细相互作用的 TDPAC 研究

  摘要：

  摘要 时差微扰角相关技术 (TDPAC) 已被用于测量在高压 (8 GPa) 和高温下合成的早期已知 RAl 3 化合物中超精细相互作用的参数，其中 R = La、Ce、Sm、 Gd、Tb、Dy、Ho、Er、Yb 和 Lu。111 Cd( 111 In) 放射性原子被用作探针核。X射线法表明，随着稀土元素R原子序数的增加，得到的RAl 3 高压相分别结晶成正交、六方和立方结构。已经发现，在含有R=La、Ce、Sm和Gd的化合物中，观察到与早期已知结构类型的偏差和新结构类型的形成，这与所述化合物的化学计量组成的变化有关。

  DOI：

  10.1016/j.ssc.2007.02.027

文献信息

• The thermal expansion and electrical resistivity of the pseudobinary compound Ce1-xLaxAl3
  作者：Tomoko Kagayama、Kōji Munakata、Gendo Oomi

  DOI：10.1016/0925-8388(93)90237-h

  日期：1993.2

  Temperature dependence of the thermal expansion coefficient alpha and the electrical resistivity rho of Ce1-xLaxAl3 compounds has been measured for various lanthanum concentrations x. It is found that the temperature dependence of alpha and rho is influenced largely by substitution of lanthanum. The results are briefly discussed in connection with the Kondo effect and crystalline electric field splitting of the 4f level of the Ce3+ ion.
• Phase equilibria in the ternary Al–Zr–La system
  作者：Dan Peng、Yongzhong Zhan、Jia She、Mingjun Pang、Yong Du

  DOI：10.1016/j.jallcom.2010.07.133

  日期：2010.9

  The phase relationships in the Al-Zr-La ternary system at 773 K have been investigated for the first time mainly by means of X-ray powder diffraction (XRD) and scanning electron microscopy (SEM) equipped with energy dispersive analysis (EDX). The existence of the Al4La5 and AlLa2 binary compounds has been confirmed in this ternary system. The isothermal section consists of 18 single-phase regions, 33 two-phase regions and 16 three-phase regions. No ternary compound was observed in this work. (C) 2010 Elsevier B.V. All rights reserved.
• High pressure X-ray diffraction study of LaAl2 and LaAl3
  作者：M Sekar、N.V Chandra Shekar、P.Ch Sahu、N.R Sanjay Kumar、K.Govinda Rajan

  DOI：10.1016/s0921-4526(02)01320-0

  日期：2002.11

  LaAl2 and LaAl3 exhibit MgCu2 type (space group Fd3m) and Ni3Sn type (space group P6(3)/mmc) structures, respectively, at NTP. High pressure X-ray diffraction studies on these two systems are carried out up to similar to35 and similar to30 GPa, respectively, with a diamond anvil cell, mounted on a high precision Guinier diffractometer. The volume compression determined at the highest pressures are about 33% for LaAl2 and 23% for LaAl3. Neither compound shows any structural transition. (C) 2002 Elsevier Science B.V. All rights reserved.
• Effect of pressure on the electrical resistivity of the heavy fermion CeAl3
  作者：Tomoko Kagayama、Takayuki Ishii、Gendo Oomi

  DOI：10.1016/0925-8388(94)90217-8

  日期：1994.6

  The electrical resistivity rho(T) of the heavy fermion compound CeAl3 has been measured under high pressure up to 1.5 GPa in order to clarify the volume dependence of the electronic state in the heavy fermion. It is found that the temperature showing a maximum in the rho(T) curve increases with increasing pressure. Compressibility was also measured using the X-ray diffraction technique at high pressure. On the basis of the data, a quantitative analysis of the volume dependent energy scale is examined using a simple theoretical model.
• Effect of Pressure on the Magnetoresistance of the Heavy Fermion Compound CeAl_<b>3</b>
  作者：Gendo Oomi、Tomoko Kagayama

  DOI：10.1143/jpsj.65.2732

  日期：1996.8.15