[1,1'-bis(benzylimino)ferrocene]palladium methyl chloride | 874534-23-3

• 英文名称: [1,1'-bis(benzylimino)ferrocene]palladium methyl chloride
• CAS: 874534-23-3
• 化学式: C₂₅H₂₃ClFeN₂Pd
• 分子量: 549.191
• InChiKey: CZLDIEHLHQCUEY-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  [1,1'-bis(benzylimino)ferrocene]palladium methyl chloride 、 四(3,5-二(三氟甲基)苯基)硼酸钠 、 乙腈 以 二氯甲烷 、 乙腈 为溶剂， 以59%的产率得到[1,1'-bis(benzylimino)ferrocene]palladium methyl acetonitrile tetrakis(3,5-bis-trifluoromethyl-phenyl)borate
  参考文献：
  名称：

  The synthesis, coordination chemistry and ethylene polymerisation activity of ferrocenediyl nitrogen-substituted ligands and their metal complexes

  摘要：

  Treatment of aminoferrocene with substituted 2-hydroxybenzaldehydes yields the air- and moisture-stable ligands 1-4, which were then reacted to form the chromium dichloride complexes 5-7 and the nickel bis-chelate species 8 and 9. The metal compounds are very air-sensitive but the chromium compounds act as pre-catalysts for the polymerisation of ethylene. Reaction of 1,1'-bis(amino)ferrocene with similarly substituted 2-hydroxybenzaldehyes or simple benzaldehyde gives the ligands 10-12 and 17, respectively. The X-ray crystal structure of 11 shows the molecule to have non-crystallographic C-2 symmetry and to be linked by C-H-...pi interactions between the anthracene rings. Titanium-containing complexes 13-16 can be formed utilising ligands 10-12 and there is a change in geometry within the complexes dependent on the adjacent co-ligands, whilst ligand 17 can be reacted with PdClMe(COD) to form the chelate complex 18. Cyclic voltammetric studies have been carried out on 18 and its oxidised analogue 19, but both complexes are inactive towards ethylene polymerisation. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2005.05.051
• 作为产物：
  描述：

  chloromethyl(1,5-cyclooctadiene)palladium(II) 、 N,N'-bis(benzaldimine)ferroceneamine 以 二氯甲烷 为溶剂， 以46%的产率得到[1,1'-bis(benzylimino)ferrocene]palladium methyl chloride
  参考文献：
  名称：

  The synthesis, coordination chemistry and ethylene polymerisation activity of ferrocenediyl nitrogen-substituted ligands and their metal complexes

  摘要：

  Treatment of aminoferrocene with substituted 2-hydroxybenzaldehydes yields the air- and moisture-stable ligands 1-4, which were then reacted to form the chromium dichloride complexes 5-7 and the nickel bis-chelate species 8 and 9. The metal compounds are very air-sensitive but the chromium compounds act as pre-catalysts for the polymerisation of ethylene. Reaction of 1,1'-bis(amino)ferrocene with similarly substituted 2-hydroxybenzaldehyes or simple benzaldehyde gives the ligands 10-12 and 17, respectively. The X-ray crystal structure of 11 shows the molecule to have non-crystallographic C-2 symmetry and to be linked by C-H-...pi interactions between the anthracene rings. Titanium-containing complexes 13-16 can be formed utilising ligands 10-12 and there is a change in geometry within the complexes dependent on the adjacent co-ligands, whilst ligand 17 can be reacted with PdClMe(COD) to form the chelate complex 18. Cyclic voltammetric studies have been carried out on 18 and its oxidised analogue 19, but both complexes are inactive towards ethylene polymerisation. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2005.05.051