bis-((μ(2)-acetato-O,O')-.mu-(N,N'-bis(o-hydroxybenzyl)-1,4-diaminobutane) nickel)nickel acetate | 926625-14-1

• 英文名称: bis-((μ(2)-acetato-O,O')-.mu-(N,N'-bis(o-hydroxybenzyl)-1,4-diaminobutane) nickel)nickel acetate
• 英文别名: ([Ni(H4Salbu)]2Ni2(OAc)4)
• CAS: 926625-14-1
• 化学式: C₄₄H₅₆N₄Ni₄O₁₂
• 分子量: 1067.71
• InChiKey: DAUBBYFRAXUVBD-UHFFFAOYSA-F

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  氯仿 、 bis-((μ(2)-acetato-O,O')-.mu-(N,N'-bis(o-hydroxybenzyl)-1,4-diaminobutane) nickel)nickel acetate 以 氯仿 为溶剂， 生成 bis-((μ(2)-acetato-O,O')-.mu-(N,N'-bis(o-hydroxybenzyl)-1,4-diaminobutane) nickel)nickel acetate - chloroform 1/0.33
  参考文献：
  名称：

  Hydrogenated Schiff base ligands: Towards the controlled organisation of open metal frameworks

  摘要：

  The synthesis and structures of bis-((mu(2)-acetato-O,O')-mu-(N,N'-bis-(o-hydroxybenzyl)-1,3-diaminopropane)-(aquo)nickel)nickel, his((mu(2) -acetato-O,O')-mu-(N,N-bis-(o-hydroxybenzyl)-1,4-diaminobutane nickel)nickel acetate) and bis-((mu(2)-acetato-O,O')-mu-(N,N-bis(o-hydroxybenzyl)-1,4-diaminobutane)-(dimethylformamido)nickel)nickel are reported. These compounds are designed to draw attention to the wider structural catalogue available to symmetrical hydrogenated Schiff base complexes which contain a tetramethylene backbone. (C) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2006.04.013
• 作为产物：
  描述：

  nickel diacetate 、 2,2'-[butane-1,4-diylbis(iminomethylene)]bis[phenol] 以 甲醇 为溶剂， 以40%的产率得到bis-((μ(2)-acetato-O,O')-.mu-(N,N'-bis(o-hydroxybenzyl)-1,4-diaminobutane) nickel)nickel acetate
  参考文献：
  名称：

  Hydrogenated Schiff base ligands: Towards the controlled organisation of open metal frameworks

  摘要：

  The synthesis and structures of bis-((mu(2)-acetato-O,O')-mu-(N,N'-bis-(o-hydroxybenzyl)-1,3-diaminopropane)-(aquo)nickel)nickel, his((mu(2) -acetato-O,O')-mu-(N,N-bis-(o-hydroxybenzyl)-1,4-diaminobutane nickel)nickel acetate) and bis-((mu(2)-acetato-O,O')-mu-(N,N-bis(o-hydroxybenzyl)-1,4-diaminobutane)-(dimethylformamido)nickel)nickel are reported. These compounds are designed to draw attention to the wider structural catalogue available to symmetrical hydrogenated Schiff base complexes which contain a tetramethylene backbone. (C) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2006.04.013