[Cu(tris(2-benzylaminoethyl)amine)(Cl)]Cl | 402507-30-6

• 英文名称: [Cu(tris(2-benzylaminoethyl)amine)(Cl)]Cl
• CAS: 402507-30-6
• 化学式: C₂₇H₃₆ClCuN₄*Cl
• 分子量: 551.062
• InChiKey: XJMGPJKDLLNQHE-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  copper(II) choride dihydrate 、 tris(2-benzylaminoethyl)amine 以 甲醇 为溶剂， 以60%的产率得到[Cu(tris(2-benzylaminoethyl)amine)(Cl)]Cl
  参考文献：
  名称：

  Reactivity towards dioxygen of a copper(I) complex of tris(2-benzylaminoethyl)amine

  摘要：

  The reaction of dioxygen with the copper(I) Bz(3)tren complex (Bz(3)tren = tris(2-benzylaminoethyl)anline) complex has been investigated using low temperature stopped-flow techniques, The formation of a superoxo as well as a peroxo complex as intermediates was detected spectroscopically. The copper(II) complexes [Cu(Bz(3)tren)H2O](ClO4)(2) and [Cu(Bz(3)tren)Cl]Cl were synthesized and structurally characterized. Both complexes react with dioxygen in solution and formation of benzaldehyde was observed. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(01)00588-6