[(μ-H)Os3(.mu-OCNMe2)(CO)9(PHPh2)] | 313689-15-5

• 英文名称: [(μ-H)Os3(.mu-OCNMe2)(CO)9(PHPh2)]
• CAS: 313689-15-5
• 化学式: C₂₄H₁₈NO₁₀Os₃P
• 分子量: 1081.98
• InChiKey: GEUQYHVWJFKKRU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  1,2-μ-hydrido-1,2-μ-(N,N-dimethylcarbamoyl)-1-trimethylamino-1,1,2,2,2,3,3,3,3-nonacarbonyl-triangulo-triosmium 、 烯丙基二苯基膦 以 二氯甲烷 为溶剂， 以68%的产率得到1-(allyldiphenylphosphine)-1,2-μ-(N,N-dimethylcarbamoyl)-1,2-μ-hydrido-1,1,2,2,2,3,3,3,3-nonacarbonyl-triangulo-triosmium
  参考文献：
  名称：

  制备，X射线结构，共聚的苯乙烯[（μ-H）O的3（μ-OCNMe 2）（CO）9 {P（CH 2 CHCH 2）PH 2 }]和群集/苯乙烯共聚物的催化性能

  摘要：

  的配合物[（μ-H）O的3（μ-OCNMe 2）（CO）9 {P（CH 2 CHCH 2）PH 2 }]从更换一轻稳定NME的衍生3在[（μ-H配位体）O的3（μ-OCNMe 2）（CO）9（NME 3）]通过烯丙基二苯基膦分子的物理化学和X射线结构表征，并进一步用作要固定在聚合物表面的金属簇单体。研究了该簇状单体与苯乙烯的共聚。已经发现，簇状分子在共聚时保持其完整性和整体结构。已测试获得的簇状共聚物作为氧化脱氢和环己烯醇羟基化反应的催化剂。

  DOI：

  10.1016/j.jorganchem.2005.06.032

文献信息

• Preparation and reactivity of metal-containing monomers 53. Synthesis and stability of a cluster monomer (μ-H)Os3(μ-OCNMe2)(CO)9PPh2CH2CH=CH2 in solution
  作者：V. A. Ershova、A. V. Golovin、L. A. Sheludyakova、P. P. Semyannikov、S. I. Pomogailo、A. D. Pomogailo

  DOI：10.1007/bf02495095

  日期：2000.8

  The stability of the complex (mu-H)Os-3(mu-OCNMe2)(CO)(9)PPh2CH2CH=CH2 (1), which contains a free unsaturated functional group in the terminal ligand PPh2CH2CH=CH2, with respect to isomerization, chelation of the ligand, and other transformations in solutions was examined. No transformations of complex 1 were observed in the course of synthesis from (mu-H)Os-3(mu-OCNMe2)(CO)(9)NMe3 or upon heating in solution. Complex 1 as well as which complexes (mu-H)Os-3(mu-OCNMe2)(CO)(9)PHPh2 and (mu-H)Os-3(mu-OCNMe2)(CO)(9)PPh3 which were formed as admixtures, were isolated in the solid state and identified by H-1,H-1-P-31}, and H-1-H-1} NMR, IR, and Raman spectroscopy and mass spectrometry.