1,2-μ-(N,N-dimethylcarbamoyl)-1,2-μ-hydrido-1-(triphenylphosphine)-1,1,2,2,2,3,3,3,3-nonacarbonyl-triangulo-triosmium | 313689-16-6

• 英文名称: 1,2-μ-(N,N-dimethylcarbamoyl)-1,2-μ-hydrido-1-(triphenylphosphine)-1,1,2,2,2,3,3,3,3-nonacarbonyl-triangulo-triosmium
• 英文别名: [(μ-H)Os3(.mu-OCNMe2)(CO)9(PPh3)]
• CAS: 313689-16-6
• 化学式: C₃₀H₂₂NO₁₀Os₃P
• 分子量: 1158.08
• InChiKey: BZUWHXIVMLKHFY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  1,2-μ-hydrido-1,2-μ-(N,N-dimethylcarbamoyl)-1-trimethylamino-1,1,2,2,2,3,3,3,3-nonacarbonyl-triangulo-triosmium 、 三苯基膦 以 二氯甲烷 为溶剂， 以82%的产率得到1,2-μ-(N,N-dimethylcarbamoyl)-1,2-μ-hydrido-1-(triphenylphosphine)-1,1,2,2,2,3,3,3,3-nonacarbonyl-triangulo-triosmium
  参考文献：
  名称：

  Preparation and reactivity of metal-containing monomers 53. Synthesis and stability of a cluster monomer (μ-H)Os3(μ-OCNMe2)(CO)9PPh2CH2CH=CH2 in solution

  摘要：

  The stability of the complex (mu-H)Os-3(mu-OCNMe2)(CO)(9)PPh2CH2CH=CH2 (1), which contains a free unsaturated functional group in the terminal ligand PPh2CH2CH=CH2, with respect to isomerization, chelation of the ligand, and other transformations in solutions was examined. No transformations of complex 1 were observed in the course of synthesis from (mu-H)Os-3(mu-OCNMe2)(CO)(9)NMe3 or upon heating in solution. Complex 1 as well as which complexes (mu-H)Os-3(mu-OCNMe2)(CO)(9)PHPh2 and (mu-H)Os-3(mu-OCNMe2)(CO)(9)PPh3 which were formed as admixtures, were isolated in the solid state and identified by H-1,H-1-{P-31}, and H-1-{H-1} NMR, IR, and Raman spectroscopy and mass spectrometry.

  DOI：

  10.1007/bf02495095

文献信息

• Preparation, X-ray structure, copolymerization with styrene of [(μ-H)Os3(μ-OCNMe2)(CO)9{P(CH2CHCH2)Ph2}] and catalytic properties of the cluster/styrene copolymer
  作者：Svetlana I. Pomogailo、Gennady V. Shilov、Victoria A. Ershova、Alexander V. Virovets、Vladimir M. Pogrebnyak、Nina V. Podberezskaya、Anatoly V. Golovin、Gulzhian I. Dzhardimalieva、Anatolii D. Pomogailo

  DOI：10.1016/j.jorganchem.2005.06.032

  日期：2005.10

  characterized and served further as a metal cluster monomer to be immobilized on a polymer surface. The copolymerization of this cluster monomer with styrene was studied. It was found that the cluster molecule, when copolymerized, maintains its integrity and the overall structure. The cluster copolymers obtained have been tested as catalysts for oxidative dehydrogenation and cyclohexenol hydroxylation

  的配合物[（μ-H）O的3（μ-OCNMe 2）（CO）9 P（CH 2 CHCH 2）PH 2 }]从更换一轻稳定NME的衍生3在[（μ-H配位体）O的3（μ-OCNMe 2）（CO）9（NME 3）]通过烯丙基二苯基膦分子的物理化学和X射线结构表征，并进一步用作要固定在聚合物表面的金属簇单体。研究了该簇状单体与苯乙烯的共聚。已经发现，簇状分子在共聚时保持其完整性和整体结构。已测试获得的簇状共聚物作为氧化脱氢和环己烯醇羟基化反应的催化剂。