cis-[PtCl2(2-(1-octyl-5-phenyl-1H-pyrazol-3-yl)pyridine)] | 876061-94-8

• 英文名称: cis-[PtCl2(2-(1-octyl-5-phenyl-1H-pyrazol-3-yl)pyridine)]
• CAS: 876061-94-8
• 化学式: C₂₂H₂₇Cl₂N₃Pt
• 分子量: 599.462
• InChiKey: BQPQMEWCLRAQNU-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  bis(acetonitrile)dichloroplatinum(II) 、 2-(1-octyl-5-phenyl-1H-pyrazol-3-yl)-pyridine 以 乙腈 为溶剂， 以40%的产率得到cis-[PtCl2(2-(1-octyl-5-phenyl-1H-pyrazol-3-yl)pyridine)]
  参考文献：
  名称：

  Reaction of [MCl2(CH3CN)2] (M=Pd(II), Pt(II)) compounds with N1-alkylpyridylpyrazole-derived ligands

  摘要：

  Palladium(II) and platinum(II) complexes with N-alkylpyridylpyrazole-derived ligands, 2-(1-ethyl-5-phenyl-1H-pyrazol-3-yl)pyridine (L-1) and 2-(1-octyl-5-phenyl-1H-pyrazol-3-yl)pyridine (L-2), cis-[MCl2(L)] (M = Pd(II), Pt(II)), have been synthesised. Treatment of [PdCl2(L)] (L = L-1, L-2) with excess of ligand (L-1, L-2), pyridine (py) or triphenylphosphine (PPh3) in the presence of AgBF4 and NaBPh4 produced the following complexes: [Pd(L)(2)](BPh4)(2), [Pd(L)(PY)(2)](BPh4)(2) and [Pd(L)(PPh3)(2)](BPh4)(2). All complexes have been characterised by elemental analyses, conductivity, IR and NMR spectroscopies. The crystal structures of cis-[PdCl2(L-2)] (2) and CiS-[PtCl2(L-1)] (3) were determined by a single crystal X-ray diffraction method. In both complexes, the metal atom is coordinated by one pyrazole nitrogen, one pyridine nitrogen and two chlorine atoms in a distorted square-planar geometry. In complex 3, pi-pi stacking between pairs of molecules is observed. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2005.07.047