1-silatranyl nitrate | 943866-30-6

• 英文名称: 1-silatranyl nitrate
• CAS: 943866-30-6
• 化学式: C₆H₁₂N₂O₆Si
• 分子量: 236.257
• InChiKey: AROFWDFXJMICGS-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  1-hydrosilatrane 在 mercury(II) nitrate 作用下， 以 乙腈 为溶剂， 以60%的产率得到1-silatranyl nitrate
  参考文献：
  名称：

  1-Silantranyl nitrate

  摘要：

  A method of synthesis of 1-silatranyl nitrate O(2)NOSi(OCH(2)CH(2))(3)N based on the reaction of 1-hydrosilatrane with mercury nitrate in the acetonitrile medium was developed. The structure of the synthesized 1-silatranyl nitrate, mp 227A degrees C, was confirmed by elemental analysis, (1)H, (13)C, and (29)Si NMR spectoscopy, infrared spectroscopy, and mass spectrometry. Silatranyl nitrate previously described in the literature as yellowish viscous oil apparently contains impurities preventing its crystallization.

  DOI：

  10.1134/s1070363210100063