[RuCl(acetonitrile)(η6-p-cymene)(P(i-Pr)2(p-Ph3BC6H4))] | 1060385-21-8

• 英文名称: [RuCl(acetonitrile)(η6-p-cymene)(P(i-Pr)2(p-Ph3BC6H4))]
• CAS: 1060385-21-8
• 化学式: C₄₂H₅₀BClNPRu
• 分子量: 747.173
• InChiKey: PEZZPUPUXWOKII-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  [Bu4N][RuCl2(η6-p-cymene)(P(i-Pr)2(p-Ph3BC6H4))] 、 乙腈 在 AgNO₃ 作用下， 以 二氯甲烷 为溶剂， 以86%的产率得到[RuCl(acetonitrile)(η6-p-cymene)(P(i-Pr)2(p-Ph3BC6H4))]
  参考文献：
  名称：

  The (phosphino)tetraphenylborate ligand in ruthenium-arene chemistry

  摘要：

  The synthesis of a series of anionic half- sandwich ruthenium- arene complexes [ E][ RuCl2( g6- p- cymene){PR2( p- Ph3BC6H4)}] ( E = Bu4N+: R = Ph, 1a, iPr, 1b or Cy, 1c; E = bis( triphenylphosphine) iminium or PNP+: R = Ph, 1a0, iPr, 1b0 or Cy, 1c0) are reported. X- ray crystallographic studies of 1a0 and 1b0 con. rmed the three- legged piano- stool coordination geometry. In solution, complexes 1a - c and 1a0 - c0 are proposed to form monomer - dimer equilibria as a result of chloride ligand dissociation. Complexes 1a - c and 1a0 - c0 also form the formally neutral zwitterionic complexes [ RuCl( L)( g6- p- cymene){PR2( p- Ph3BC6H4)}] ( L = pyridine: R = Ph, 2a, iPr, 2b or Cy, 2c; L = MeCN: R = Ph, 3a, iPr, 3b or Cy, 3c) via chloride ligand abstraction using AgNO3 or MeOTf. (c) 2008 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2008.06.013