Bis(N-isopropyl-1,2-ethanediamine)Copper(II)Tetrafluoroborate | 259734-62-8

• 英文名称: Bis(N-isopropyl-1,2-ethanediamine)Copper(II)Tetrafluoroborate
• CAS: 259734-62-8
• 化学式: BF₄*C₁₀H₂₈BCuF₄N₄
• 分子量: 441.514
• InChiKey: CSSBDVQGWQFELQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  copper(II) bis(tetrafluoroborate) 、 N-异丙基乙二胺 以 乙醇 为溶剂， 生成 Bis(N-isopropyl-1,2-ethanediamine)Copper(II)Tetrafluoroborate
  参考文献：
  名称：

  Structural studies on Cu(N,N-dialkyldiamine)2X2 complexes: X-ray structure of bis(N-isopropyl-1,2-ethanediamine) copper(II)tetrafluroborate

  摘要：

  Bis(N-isopropyl-1,2-ethanediamine)Copper(II)Tetrafluoroborate has been investigated by single crystal X-ray diffraction methods. The Cu2+ ion has a tetragonally distorted square pyramidal type geometry; where the four N-atoms of the Ligand molecules are equatorial [Cu-N1 = 2.031(5) Angstrom and 2.004(5) Angstrom] and the fifth apical coordination is from one of the F-atom of the BF4- counter-ion [Cu ... F3 = 2.527(5) Angstrom]. The semi-coordinated nature of the polyanion has been interpreted by IR studies and the structure-thermochromic property is correlated and discussed in terms of hydrogen bonding and anion interaction. (C) 2000 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-2860(99)00201-x