[Ho(2-fluorobenzoato)3(1,10-phenanthroline)(CH3CH2COOH)]2*[Ho(2-fluorobenzoato)3(1,10-phenanthroline)]2 | 866482-35-1

• 英文名称: [Ho(2-fluorobenzoato)3(1,10-phenanthroline)(CH3CH2COOH)]2*[Ho(2-fluorobenzoato)3(1,10-phenanthroline)]2
• 英文别名: [Ho(2-FBA)3(phen)(CH3CH2OH)]2*[Ho(2-FBA)3(phen)]2
• CAS: 866482-35-1
• 化学式: C₆₆H₄₀F₆Ho₂N₄O₁₂*C₇₀H₅₂F₆Ho₂N₄O₁₄
• 分子量: 3141.97
• InChiKey: DERXMQAMHPWCCD-UHFFFAOYSA-B

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  [Ho(2-fluorobenzoato)3(1,10-phenanthroline)(CH3CH2COOH)]2*[Ho(2-fluorobenzoato)3(1,10-phenanthroline)]2 以 neat (no solvent) 为溶剂， 生成 holmium(III) oxide
  参考文献：
  名称：

  Synthesis, crystal structure and properties of three new holmium 2-fluorobenzoato complexes

  摘要：

  This paper reports three new holmium 2-fluorobenzoato (2-FBA) complexes with 1,10-phenanthroline (phen), 2,2'-bipydine (2,2'-bpy) and 4,4'-bipyridine, respectively. A rare and interesting structural feature of holmium 2-FBA complex containing phen is two non-equivalent binuclear molecules existed in an asymmetric unit, namely, [Ho(2-FBA)(3)center dot phen center dot CH3CH2OH](2) and [Ho(2-FBA)(3)center dot phen](2). The dimeric complex [Ho(2-FBA)(3)center dot 2,2-bpy](2) is a type of eight-coordinated lanthanide carboxylate complexes containing 2,2-bpy. The {[Ho(2-FBA)(3)center dot 2H(2)O]center dot(4,4'-bpy)}(n) is in one-dimensional polymeric structure, and the 3D supramolecular network structure is formed by the hydrogen bonds and pi-pi stacking interactions. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2005.05.005
• 作为产物：
  描述：

  1,10-菲罗啉 、 holmium(III) chloride hexahydrate 、 乙醇 、 邻氟苯甲酸 在 NaOH 作用下， 以 乙醇 为溶剂， 生成 [Ho(2-fluorobenzoato)3(1,10-phenanthroline)(CH3CH2COOH)]2*[Ho(2-fluorobenzoato)3(1,10-phenanthroline)]2
  参考文献：
  名称：

  Synthesis, crystal structure and properties of three new holmium 2-fluorobenzoato complexes

  摘要：

  This paper reports three new holmium 2-fluorobenzoato (2-FBA) complexes with 1,10-phenanthroline (phen), 2,2'-bipydine (2,2'-bpy) and 4,4'-bipyridine, respectively. A rare and interesting structural feature of holmium 2-FBA complex containing phen is two non-equivalent binuclear molecules existed in an asymmetric unit, namely, [Ho(2-FBA)(3)center dot phen center dot CH3CH2OH](2) and [Ho(2-FBA)(3)center dot phen](2). The dimeric complex [Ho(2-FBA)(3)center dot 2,2-bpy](2) is a type of eight-coordinated lanthanide carboxylate complexes containing 2,2-bpy. The {[Ho(2-FBA)(3)center dot 2H(2)O]center dot(4,4'-bpy)}(n) is in one-dimensional polymeric structure, and the 3D supramolecular network structure is formed by the hydrogen bonds and pi-pi stacking interactions. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2005.05.005