1-cymantrenyl-3,5-diferrocenylbenzene | 1035404-78-4

• 英文名称: 1-cymantrenyl-3,5-diferrocenylbenzene
• CAS: 1035404-78-4
• 化学式: C₃₄H₂₅Fe₂MnO₃
• 分子量: 648.203
• InChiKey: PQCJVADARZICDT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  乙酰基二茂铁 、 (acetylcyclopentadienyl)tricarbonylmanganese 在 四氯化硅 sodium bicarbonate 作用下， 以 乙醇 为溶剂， 生成 1,3,5-triferrocenyl benzene 、 1,3-diferrocenyl-3-methylprop-2-enone 、 1,3,5-tricymantrenylbenzene 、 1-cymantrenyl-3,5-diferrocenylbenzene 、 1,3-dicymantrenyl-5-ferrocenylbenzene
  参考文献：
  名称：

  An investigation of the formation of 1,3,5-heterosubstituted benzene rings by cyclo-condensation of acetyl-substituted organometallic complexes

  摘要：

  The cyclocondensation of acetylferrocene and acetylcymantrene catalyzed by SiCl(4) in ethanol yields a mixture of 1,3,5-trisubstituted benzenes and the intermediate 3,1-disubstituted (E)-2-buten-1-ones, including all the homo- and heterometallic species, which were separated and quantified by HPLC. The relative yields of these species are determined by the different ability of the organometallic groups to stabilize the cationic intermediates that participate in the reaction mechanism, which is measurable as the basicity of the starting materials. The X-ray crystal structures of 1-cymantrenyl-3,5-diferrocenylbenzene and (E)-3-cymantrenyl-1-ferrocenyl-2-buten-1-one are described within this report. (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2008.02.013