Zn(1-(2-pyridyl)-2-(2-thienyl)ethyne)2Cl2 | 200195-87-5

• 英文名称: Zn(1-(2-pyridyl)-2-(2-thienyl)ethyne)2Cl2
• CAS: 200195-87-5
• 化学式: C₂₂H₁₄Cl₂N₂S₂Zn
• 分子量: 506.795
• InChiKey: UIDHIGQEZOYQLT-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2-(thiophen-2-ylethynyl)pyridine 、 zinc(II) chloride 以 乙醇 为溶剂， 生成 Zn(1-(2-pyridyl)-2-(2-thienyl)ethyne)2Cl2
  参考文献：
  名称：

  Coordination compounds of the rigid rod ligand 1-(2-pyridyl)-2-(2-thienyl)ethyne (pythio). Single crystal X-ray structures of [Cu(pythio)2(NO3)2] and [Zn(pythio)2Cl2]

  摘要：

  Four new compounds of the ligand 1-(2-pyridyl)-2-(2-thienyl)ethyne (pythio), viz. [M(pythio)(2)(NO3)(2)] (M = Cu, Co and Ni) and [Zn(pythio)(2)Cl-2] are described. The compounds, prepared from the ligand and the metal salts in acetone or ethanol, are 2:1 ligand:metal complexes wherein the ligand acts as a monodentate nitrogen donor ligand. The single-crystal X-ray structures of the Cu and the Zn compounds show an elongated octahedral CuN2O2O2' chromophore and a tetrahedral ZnN2Cl2 chromophore. The coordination appears not to be influenced by the acetylene groups or by the thiophene groups. (C) 1998 Elsevier Science S.A.

  DOI：

  10.1016/s0020-1693(97)05612-0