| 162410-85-7

• CAS: 162410-85-7
• 化学式: C₃₆H₂₂FeN₄O₂*F₆P
• 分子量: 743.407
• InChiKey: WYGKCRXQBJARMQ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  六氟磷酸钾 、 iron(II) chloride tetrahydrate 、 2-(2-hydroxyphenyl)-1,10-phenanthroline 以 甲醇 为溶剂， 以90%的产率得到
  参考文献：
  名称：

  The coordination chemistry of mixed pyridine-phenol and phenanthroline-phenol ligands; The crystal structure of 2-(2-hydroxyphenyl)-1,10-phenanthroline (HL) and the crystal structure and properties of [FeL2][PF6]

  摘要：

  The crystal structures of the N,N,O-terdentate ligand 2-(2-hydroxyphenyl)-1,10-phenanthroline (HL) and its Fe(III) complex [FeL(2)][PF6] (1) have been determined. In HL, an intramolecular O-H ... N hydrogen bond between the phenolic OH and the adjacent nitrogen atom of the phenanthroline fragment constrains these two donor atoms to be cisoid, with the proton 'chelated'. The molecules of HL are associated into pairs in the crystal via a face-to-face aromatic pi-stacking interaction. Complex 1 has a conventional distorted octahedral structure; sections of the aromatic ligands overlap between adjacent molecules to form an interleaved stack. It is high-spin down to 83 K, and its EPR spectrum (frozen glass at 77 K) is entirely typical of a rhombically distorted high-spin Fe-III site.

  DOI：

  10.1016/0277-5387(94)00281-i