摘要:
New silver(I) beta-diketiminate complexes have been prepared and characterized. Monomeric complexes with ethylene (4), triphenylphosphine (5), and IMes (IMes = 1,3-dimesitylimidazol-2-ylidene) (8) as well as a dinuclear acetonitrile complex (3) were characterized by H-1 NMR, C-13 NMR, elemental analysis, and X-ray crystallography. These complexes are stable in the solid state at ambient temperature and inert atmosphere.