trans,cis-[RuCl(CO)(dppb)(phen)]PF6*CH2Cl2 | 1243693-42-6

• 英文名称: trans,cis-[RuCl(CO)(dppb)(phen)]PF6*CH2Cl2
• 英文别名: trans,cis-[RuCl(CO)(1,4-bis(diphenylphosphino)butane)(1,10-phenanthroline)]PF6*CH2Cl2
• CAS: 1243693-42-6
• 化学式: CH₂Cl₂*C₄₁H₃₆ClN₂OP₂Ru*F₆P
• 分子量: 1001.12
• InChiKey: IPWFVSRACMKXDA-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  ammonium hexafluorophosphate 、 1,10-菲罗啉 、 二氯甲烷 、 [Ru₂(1,4-bis(diphenylphosphino)butane)₃(CO)₂Cl₄] 以 甲醇 为溶剂， 以60%的产率得到trans,cis-[RuCl(CO)(dppb)(phen)]PF6*CH2Cl2
  参考文献：
  名称：

  On the synthesis and structures of the complexes [RuCl(L)(dppb)(N–N)]PF6 (L = CO, py or 4-NH2py; dppb = 1,4-bis(diphenylphosphino)butane; N–N = 2,2′-bipyridine or 1,10-phenanthroline) and [(dppb)(CO)Cl2-Ru-pz-RuCl2(CO)(dppb)] (pz = pyrazine)

  摘要：

  The "Ru(P-P)" unit (P-P = diphosphine) is recognized to be an important core in catalytic species for hydrogenation of unsaturated organic substrates. Thus, in this study we synthesized six new complexes containing this core, including the binuclear complex [(dppb)(CO)Cl2Ru-pz-RuCl2(CO)(dPPb)] (pz = pyrazine) which can be used as a precursor for the synthesis of cationic carbonyl species of general formula [RuCl(CO)(dppb)(N-N)]PF6 (N-N = diimine). Complexes with the formula (RuCl(py)(dppb)(N-N)]PF6 were synthesized by exhaustive electrolysis of these carbonyl compounds or from the precursors [RuCl2(dppb)(N-N)]. The new complexes were characterized by microanalysis, conductivity measurements, IR and P-31{H-1)} NMR spectroscopy, cyclic voltammetry and X-ray crystallography. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2010.04.028