| 139028-70-9

• CAS: 139028-70-9
• 化学式: C₁₀H₁₃Cl₂GaN₄S
• 分子量: 361.935
• InChiKey: LIWZYMOWVWHYNU-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2-acetylpyridine 4,4-dimethylthiosemicarbazone 、 氯化镓 以 乙醇 为溶剂， 生成 、 Ga(2-acetylpyridine (4,4)N,N-dimethyl thiosemicarbazone)2(CaCl4)
  参考文献：
  名称：

  Synthesis and structural studies of gallium(III) and indium(III) complexes of 2-acetylpyridine thiosemicarbazones

  摘要：

  Four 2-acetylpyridine 4N-alkyl thiosemicarbazones, and their Ga(III) and In(III) complexes have been prepared and characterised by fluorescence, UV-Vis, IR, H-1 and C-13 NMR spectroscopy, mass spectrometry and X-ray crystallographic analysis. Comparison of the crystal structures gave an insight into the nature of the complexes formed, demonstrating a preference for [ML2](+) type complexes with gallium and [MLX3] species with indium. Stability studies on two candidates indicated that complex [(InLCl2MeOH)-Cl-3] was stable to chemical degradation for prolonged periods in human serum, giving this complex potential for further biological evaluation. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2009.10.020