[(ferrocenyl)COC(CH2OH)(CH2OAc)CH3] | 1058730-06-5

• 英文名称: [(ferrocenyl)COC(CH2OH)(CH2OAc)CH3]
• CAS: 1058730-06-5
• 化学式: C₁₇H₂₀FeO₄
• 分子量: 344.19
• InChiKey: WAAYLEOHLIIDSV-CURYUGHLSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  二茂铁 、 2,2-bis(acetoxymethyl)propionic acid chloride 在 AlCl₃ 作用下， 以 二氯甲烷 为溶剂， 以17%的产率得到[(ferrocenyl)COC(CH2OAc)2CH3]
  参考文献：
  名称：

  A neo-pentyl-ferrocene motif for the synthesis of electroactive polyesters

  摘要：

  Several new neo-pentylenediol based ferrocenyl molecules have been prepared using Friedel-Crafts acylation and Clemmensen reduction techniques. The acyl or methyl linker by which the ferrocenyl group is attached tunes the redox properties of the small molecule. The X-ray crystal structure of the acylferrocene with protecting ester groups, its derivative dialcohol, and the methylferrocene dialcohol compounds are reported. Melt polymerisation conditions result in an elimination from the acyl monomer, but a mild carbodiimide coupling protocol successfully generates a number of neo-pentylenediol/aromatic dicarboxylate polyesters with pendant ferrocenyl groups. (c) 2008 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2008.05.019