2-[9-(N,N-dimethylamino)]ethoxy-1,3,2-dioxaphosphorinane | 312296-46-1

• 英文名称: 2-[9-(N,N-dimethylamino)]ethoxy-1,3,2-dioxaphosphorinane
• 英文别名: 2-(1,3,2-dioxaphosphinan-2-yloxy)-N,N-dimethylethanamine
• CAS: 312296-46-1
• 化学式: C₇H₁₆NO₃P
• 分子量: 193.183
• InChiKey: SJRUMVSUAZZVFL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.2
• 重原子数：
  12
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  30.9
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  di(rhodium)tetracarbonyl dichloride 、 2-[9-(N,N-dimethylamino)]ethoxy-1,3,2-dioxaphosphorinane 以 二氯甲烷 为溶剂， 以91%的产率得到carbonylchloro<2-[9-(N,N-dimethylamino)]ethoxy-1,3,2-dioxaphosphorinane>rhodium
  参考文献：
  名称：

  Gavrilov, Russian Journal of Inorganic Chemistry, 1996, vol. 41, # 11, p. 1760 - 1764

  摘要：

  DOI：

文献信息

• Complexation properties of aminophosphites bearing phosphorus and nitrogen atoms included in six-membered cycles
  作者：Andrei V Korostylev、Oleg G Bondarev、Andrew Yu Kovalevsky、Pavel V Petrovskii、Vadim A Davankov、Konstantin N Gavrilov

  DOI：10.1016/s0020-1693(00)00351-0

  日期：2001.1

  A series of amino phosphites having phosphorus or/and nitrogen atoms, which are included in a six-membered cycle, has been synthesized. The presence of such cycles in these P,N-bidentate ligands has been shown to strongly influence the ways of their coordination with Rh(I) and Pd(II) atoms. The resulting chelate complexes have been found to be less stable when the six-membered chelate metalacycle formed and the initial cycle of the ligand molecule comprise a bicyclic system with the phosphorus or nitrogen atom being as a spiro atom. (C) 2001 Elsevier Science B.V. All rights reserved.