| 1223449-29-3

• CAS: 1223449-29-3
• 化学式: C₁₆H₂₉Fe₂NO₆P₂S₂
• 分子量: 569.183
• InChiKey: ZGWCFVSLCHFROB-CFYCIBGSSA-L

反应信息

• 作为反应物：
  描述：

  在 四氟硼酸-二乙醚络合物 作用下， 以 二氯甲烷 为溶剂， 以27%的产率得到
  参考文献：
  名称：

  An Air‐Stable Fe ₃ S ₄ Complex with Properties Similar to Those of the H _OX ^air State of the Diiron Hydrogenases

  摘要：

  AbstractA Fe3S4 complex bridged by azapropanedithiolate (adt), complex 6, was prepared as a potential model of the HOXair state of [FeFe]‐hydrogenases. Complex 6 was characterized by IR and 1H NMR spectroscopy, and its structure was determined by X‐ray crystallography. The electrochemical studies show that complex 6 is redox‐active under acidic conditions, which provides insight into the catalytic mechanism. Hydrogen evolution, driven by visible light, was observed in CH3CN/D2O solution by online mass spectroscopy.

  DOI：

  10.1002/ejic.201200632