syn-[2,2-bis(3-isopropyl-η(5)-cyclopentadienyl)propane]dichlorotitanium | 167556-13-0

• 英文名称: syn-[2,2-bis(3-isopropyl-η(5)-cyclopentadienyl)propane]dichlorotitanium
• CAS: 167556-13-0
• 化学式: C₁₉H₂₆Cl₂Ti
• 分子量: 373.201
• InChiKey: QMPMTKNHJJIDCT-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  盐酸 、 titanium(III) chloride tetrahydrofuran 、 2,2-bis(3-isopropyl-cyclopentadienyl)propane, lithium salt 以30%的产率得到syn-[2,2-bis(3-isopropyl-η(5)-cyclopentadienyl)propane]dichlorotitanium
  参考文献：
  名称：

  syn-[2,2-Bis(3-isopropyl-η5-cyclopentadienyl)propane]dichlorotitanium

  摘要：

  The title complex, [TiCl2(C19H26)], belongs to the short-bridged ansa-metallocene family, members of which are useful in polymerization processes. It was obtained in a three-step reaction sequence from 2,2-bis(cyclopentadienyl)propane in moderate overall yield. The most important structural feature is the distortion in the angles caused by the short bridge; the two isopropyl groups do not contribute significantly to the intramolecular tension in the molecule.

  DOI：

  10.1107/s0108270194014083