| 1550205-16-7

• CAS: 1550205-16-7
• 化学式: C₃₆H₃₄Cl₂N₂Pd
• 分子量: 672.005
• InChiKey: MFRBWJVQZSJWGJ-BOXWNSCSSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  双(乙腈)氯化钯(II) 、 4,5-bis(2,6-diethylphenylimino)pyrenylidene 以 二氯甲烷 为溶剂， 反应 12.0h， 以17.2%的产率得到
  参考文献：
  名称：

  Dichloropalladium complexes ligated by 4,5-bis(arylimino)pyrenylidenes: Synthesis, characterization, and catalytic behavior towards Heck-reaction

  摘要：

  A series of 4,5-bis(arylimino)pyrenylidenylpalladium(II) chloride complexes (C1-C4) were synthesized and characterized by FT-IR and NMR spectroscopy, elemental analysis as well as by single crystal X-ray diffraction for the representative complexes C1 and C3, which revealed a square planar geometry at the palladium center. All palladium complexes exhibited high activity for the Heck cross-coupling reaction, which were effective when conducted in various solvents. Furthermore, the in-situ mixture of palladium dichloride and the ligand (L1) provided an effective catalytic system for the Heck-reaction. (C) 2013 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2013.08.006