| 433976-51-3

• CAS: 433976-51-3
• 化学式: C₂₅H₄₂Cl₂NPPd
• 分子量: 564.915
• InChiKey: IEZBRKWLHVYUJE-NZPJRRIMSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  dichloro(cycloocta-1,5-diene)palladium (II) 、 N-(2-ditert-butylphosphanylcyclopenten-1-yl)-2,6-di(propan-2-yl)aniline 以 二氯甲烷 为溶剂， 以50%的产率得到
  参考文献：
  名称：

  Synthesis of New Phosphine Imine Ligands and Their Effects on the Thermal Stability of Late-Transition-Metal Olefin Polymerization Catalysts

  摘要：

  A series of a-phosphine imine hybrid ligands was successfully synthesized by nucleophilic substitution of di-tert-butylchlorophosphine or diphenylehlorophosphine on imine anions. These ligands exist as a-phosphine enamines before complexation, which tautomerize to a-phosphine imines upon coordination to Ni(II) or Pd(II). The Ni(II) and Pd(II) complexes with these PAN ligands were prepared and fully characterized by NMR, elemental analysis, and single-crystal X-ray crystallography. While all the Ni(II)-Pboolean ANDN complexes assume tetrahedral coordination geometry, the Pd(II)-PAN complexes are square planar. Upon activation with MAO, the Ni(II) complexes were active for ethylene polymerization. Whereas the Ni(II)-Pboolean ANDN complexes are less productive than the Brookhart Ni(II)-alpha-bis(imine) complexes and form polyethylenes with relatively low molecular weight, the thermal stabilities of these complexes upon activation are significantly higher than those of the corresponding Ni(II)-a-bis(imine) complexes. C-13 NMR shows that the polyethylenes are highly branched and have branch-on-branches. In contrast, the Pd(II)-Pboolean ANDN complexes were inactive for ethylene polymerization.

  DOI：

  10.1021/om020240i