[PdCl2((EtO)2Si(CH2PPh2)2)] | 862668-27-7

• 英文名称: [PdCl2((EtO)2Si(CH2PPh2)2)]
• CAS: 862668-27-7
• 化学式: C₃₀H₃₄Cl₂O₂P₂PdSi
• 分子量: 693.958
• InChiKey: PZFYGQYJMBBHCC-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  (EtO)2Si(CH2PPh2)2 、 二(氰基苯)二氯化钯 以 甲苯 为溶剂， 以85.3%的产率得到[PdCl2((EtO)2Si(CH2PPh2)2)]
  参考文献：
  名称：

  Synthesis, structure, immobilization and solid-state NMR of new dppp- and tripod-type chelate linkers

  摘要：

  Chelating phosphines incorporating ethoxysilane functions for immobilizations have been synthesized and fully characterized. (EtO)si(CH2PPh2)(3), (EtO)(2)Si(CH2PPh2)(2), and Si(CH2PPh2)(4) could be prepared in high yields from cheap starting materials. The ethoxysilanes, as well as a Pd complex thereof have been characterized by X-ray structures, and immobilized on silica. The success of the immobilization was proved by P-31 solid-state NMR of the dry materials and of the suspensions. Two representative chelate metal complexes, (EtO)(2)Si(CH2PPh2)(2)PdCl2 and (EtO)Si(CH2PPh2)(3)W(CO)(3) have been synthesized, characterized and immobilized. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2005.04.021