[Ir{N(i-Pr₂PS)₂}(coe)₂] | 900152-28-5

• 英文名称: [Ir{N(i-Pr₂PS)₂}(coe)₂]
• 英文别名: Ir(COE)(N(i-Pr2PS)2；Ir(cyclooctene)(N(i-Pr2PS)2
• CAS: 900152-28-5
• 化学式: C₂₈H₅₆IrNP₂S₂
• 分子量: 725.059
• InChiKey: IKMWZQVEWHJMON-VIBDZMCESA-N

反应信息

• 作为反应物：
  描述：

  [Ir{N(i-Pr₂PS)₂}(coe)₂] 、 [Ru^VI[Co(η⁵-C₅H₅){PO(OEt)₂}₃](N)Cl₂] 以 二氯甲烷 为溶剂， 反应 3.0h， 以62%的产率得到[(coe){N(i-Pr₂PS)₂}Ir(μ-N)Ru(L_OEt)Cl₂]
  参考文献：
  名称：

  氧和硫供体配体支持的异金属铱、铑和钌氮化络合物

  摘要：

  杂金属 M-N-Ru (M=Ir, Rh, Ru) 配合物由含有 O/S 供体配体的有机金属配合物与氮化钌 (VI) 的反应合成。X 射线晶体学表明 M-N-Ru 单元中存在广泛的 π 离域。已经研究了影响异金属氮化物配合物中键合的因素。

  DOI：

  10.1002/ejic.202200051
• 作为产物：
  描述：

  chlorobis(cyclooctene)-iridium(I) dimer 、 K[iPr2P(S)NP(S)iPr2] 以 乙醚 为溶剂， 以57%的产率得到[Ir{N(i-Pr₂PS)₂}(coe)₂]
  参考文献：
  名称：

  Iridium and rhodium complexes containing dichalcogenoimidodiphosphinato ligands

  摘要：

  Treatment of [MCl(CO)(PPh3)(2)] with K[N(R(2)PQ)(2)] afforded [M{N(Ph(2)PQ)(2)}(CO)(PPh3)] (M = Ir, Rh; Q = S, Se). The IR C=O stretching frequencies for [M(CO)(PPh3){N(Ph(2)PQ)(2)]} were found to decrease in the order S > Se. Treatment of [M(COD)Cl](2) with K[N(Ph(2)PQ)(2)] afforded [M(COD){N(Ph(2)PQ)(2)}] (COD = 1,5-cyclooctadiene; M = Ir, Rh; Q = S, Se). Treatment of [Ir(ol)(2)Cl] with K[N(Pr(2)(i)pQ)(2)] afforded [Ir(ol)(2){N(Pr(2)(i)PQ)(2)}](2) (ol = cyclooctene COE, C2H4; Q = S, Se). Oxidative addition of [Ir(CO)(PPh3)K[N((Ph2S)-S-i)(2)}] and [Ir(COD){N(Ph2PS)(2)}] with HCl afforded [Ir(H)(Cl)(CO)(PPh3){N(Ph2PS)(2)}] and trans-[Ir(H)(Cl)(COD){N(Ph2PS)(2)}], respectively. Oxidative addition of [Ir(CO)(PPh3){N(Ph2PS)(2)}] with MeI afforded [Ir(Me)(I)(CO)(PPh3)(N(Ph2PS)(2)}]. Treatment of [Ir(COE)(2)Cl](2) with K[N(R2PO)(2)] afforded [Ir(COE)(2){N(Ph2PO)(2)}] that reacted with MeOTf (OTf = triffate) to give [Ir{N(Ph2PO)(2)}(COE)(2)(Me)(OTf)]. The crystal structures of [Ir(CO)(PPh3){N(Ph2PS)(2)}], [M(COD){N(Ph2PS)(2)}] (M = Ir, Rh), [Ir(ol)(2){N((Pr2PS)-P-i)(2)}](ol = COE, C2H4), trans-[Ir(H)(Cl)(COD){N(Ph2PS)(2)}], and [Ir(COE)(2){N(Ph2PO)(2)}] have been determined. (c) 2005 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2005.10.021