(phenylphosphino-bis-3-pyridylcarbinol)Ag(tetrafluoroborate) | 847228-50-6

• 英文名称: (phenylphosphino-bis-3-pyridylcarbinol)Ag(tetrafluoroborate)
• CAS: 847228-50-6
• 化学式: Ag*BF₄*C₁₈H₁₇N₂O₂P
• 分子量: 518.992
• InChiKey: WMICEJLIPWGDQI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (phenylphosphino-bis-3-pyridylcarbinol)Ag(tetrafluoroborate) 以 not given 为溶剂， 生成 银
  参考文献：
  名称：

  Anion-Dependent Silver(I) Coordination Polymers of the Tridentate Pyridylphosphonite:  PPh(3-OCH₂C₅H₄N)₂

  摘要：

  Three new multidimensional coordination polymers have been constructed from the reaction of AgX, where X = OTf-, BF4-, or tfa(-), with the novel phosphonite PhP(3-OCH2C5H4N)(2), PCP-32, 1. It is seen that regardless of the ratio of reactants mixed, polymeric growth of the compounds always reveals a ligand-to-metal ratio of 1:2 for PCP-32AgOTf, 2, 1:1 for PCP-32AgBF(4), 3, and 1:2 for PCP-32Ag(tfa), 4. The coordination number, metal environment, ligand conformation, and polymer dimensionality are found to vary greatly from 2 to 4 and are dependent upon the anion present. Coordination numbers from 2 to 4, representing linear, trigonal, and distorted tetrahedral environments are displayed. PCP-32AgOTf polymerizes as a linear chain containing both two- and four-coordinate silvers, PCP-32AgBF(4) repeats a single trigonal motif throughout its structure, and PCP-32Ag(tfa) shows two unique distorted tetrahedral silver centers. Ligand flexibility allows for cross-ligand Ag-Ag distances to range from 3.1918(8) to 14.015(2) Angstrom. The coordination polymers have been characterized by elemental analysis, variable-temperature multinuclear NMR spectroscopy, single-crystal X-ray diffraction, and fluorometric studies.

  DOI：

  10.1021/ic0486365
• 作为产物：
  描述：

  phenylphosphino-bis-3-pyridylcarbinol 、 silver tetrafluoroborate 以 乙腈 为溶剂， 以93%的产率得到(phenylphosphino-bis-3-pyridylcarbinol)Ag(tetrafluoroborate)
  参考文献：
  名称：

  Anion-Dependent Silver(I) Coordination Polymers of the Tridentate Pyridylphosphonite:  PPh(3-OCH₂C₅H₄N)₂

  摘要：

  Three new multidimensional coordination polymers have been constructed from the reaction of AgX, where X = OTf-, BF4-, or tfa(-), with the novel phosphonite PhP(3-OCH2C5H4N)(2), PCP-32, 1. It is seen that regardless of the ratio of reactants mixed, polymeric growth of the compounds always reveals a ligand-to-metal ratio of 1:2 for PCP-32AgOTf, 2, 1:1 for PCP-32AgBF(4), 3, and 1:2 for PCP-32Ag(tfa), 4. The coordination number, metal environment, ligand conformation, and polymer dimensionality are found to vary greatly from 2 to 4 and are dependent upon the anion present. Coordination numbers from 2 to 4, representing linear, trigonal, and distorted tetrahedral environments are displayed. PCP-32AgOTf polymerizes as a linear chain containing both two- and four-coordinate silvers, PCP-32AgBF(4) repeats a single trigonal motif throughout its structure, and PCP-32Ag(tfa) shows two unique distorted tetrahedral silver centers. Ligand flexibility allows for cross-ligand Ag-Ag distances to range from 3.1918(8) to 14.015(2) Angstrom. The coordination polymers have been characterized by elemental analysis, variable-temperature multinuclear NMR spectroscopy, single-crystal X-ray diffraction, and fluorometric studies.

  DOI：

  10.1021/ic0486365