[(η5-pentamethylcyclopentadienyl)Ru(μ,η5:η6-indenyl)Ru(η5-indenyl)][PF6] | 139550-03-1

• 英文名称: [(η5-pentamethylcyclopentadienyl)Ru(μ,η5:η6-indenyl)Ru(η5-indenyl)][PF6]
• CAS: 139550-03-1
• 化学式: C₂₈H₂₉Ru₂*F₆P
• 分子量: 712.642
• InChiKey: QKYZJWFRMKDWJA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  thallium(I) hexafluorophosphate 、 chloro(pentamethylcyclopentadienyl)ruthenium(II) tetramer 、 [(η5-indenyl)Ru(μ,η5:η6-indenyl)Co(η4-tetramethylcyclobutadiene)][PF6] 以 硝基甲烷 为溶剂， 以60%的产率得到[(η5-C5Me5)Ru(μ,η5:η6-indenyl)Ru(μ,η5:η6-indenyl)Ru(η5-C5Me5)][PF6]2
  参考文献：
  名称：

  Slipped μ‐Indenyl Triple‐Decker Complexes Containing (C ₄ Me ₄ )Co and (C ₅ R ₅ )Ru Fragments

  摘要：

  AbstractSlipped triple‐decker complexes with a bridging indenyl ligand, namely [Cb*Co(μ:η5:η6‐C9H7)CoCb*]+ (2, Cb* = C4Me4) and [Cb*Co(μ:η5:η6‐C9H7)Ru(C5R5)]+ (R = H, 5a; Me, 5b), have been synthesised by electrophilic stacking of [Cb*Co(η5‐C9H7)] (1) with [Cb*Co(MeCN)3]+ or [(C5R5)Ru(MeCN)3]+ (R = H, Me), respectively. A similar reaction of [(C5R5)Ru(η5‐C9H7)] (R = H, 3a; Me, 3b) with [Cb*Co(MeCN)3]+ affords the cations [(C5R5)Ru(μ:η5:η6‐C9H7)CoCb*]+ (R = H, 4a; Me, 4b), which are isomeric with 5a,b. Stacking of [Ru(η5‐C9H7)2] (7) with [Cb*Co(MeCN)3]+ or [Cb*CoI]x/TlBF4 gives the triple‐decker complex [(η5‐C9H7)Ru(μ:η5:η6‐C9H7)CoCb*]+ (8). Further reaction of 8 with [Cp*RuCl]4/TlBF4 unexpectedly affords the slipped tetra‐decker ruthenium complex [Cp*Ru(μ:η5:η6‐C9H7)Ru(μ:η5:η6‐C9H7)RuCp*]2+ (11). The structures of [4b][Co(η‐7,8‐C2B9H11)2] and [Cp*Ru(η6‐C9H7)] (6) have been determined by X‐ray diffraction, and the electrochemical behaviour of the complexes prepared has been studied. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)

  DOI：

  10.1002/ejic.200600264