cis-dichloro[5-benzyl-3-phenyl-2-(2-pyridyl-κN)thiazolidin-4-one-κS]paladium(II) | 500711-71-7

• 英文名称: cis-dichloro[5-benzyl-3-phenyl-2-(2-pyridyl-κN)thiazolidin-4-one-κS]paladium(II)
• CAS: 500711-71-7
• 化学式: C₂₁H₁₈Cl₂N₂OPdS
• 分子量: 523.779
• InChiKey: JUPHGWSTUBBMJK-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  bis(acetonitrile)palladium(II) dichloride 、 5-benzyl-3-phenyl-2-(2-pyridyl)thiazolidin-4-one 以 二氯甲烷 为溶剂， 生成 cis-dichloro[5-benzyl-3-phenyl-2-(2-pyridyl-κN)thiazolidin-4-one-κS]paladium(II)
  参考文献：
  名称：

  [5-Benzyl-3-phenyl-2-(2-pyridyl-κN)thiazolidin-4-one-κS]dichloropalladium(II)

  摘要：

  The palladium(II) centre in the title compound, [PdCl2 (C21H18 N2OS)], is coordinated to the pyridyl N atom and to the thiazolidinone S atom of the 5-benzyl-3-phenyl-2-(2-pyridyl)thiazolidin-4-one ligand, resulting in a five-membered chelate ring. Two cis-chloro ligands complete the square-planar coordination environment of the metal. Although the geometry at the Pd centre is essentially planar, the N-Pd-S bite angle of 85.20 (8)degrees causes deviations in the cis angles from the ideal value of 90degrees. Opposite enantiomers form one-dimensional chains in the cell via a short S...O intermolecular interaction.

  DOI：

  10.1107/s0108270102019224