[PdCl2(2,2'-bis(diphenylphosphinomethyl)propionic acid)] | 1052093-88-5

• 英文名称: [PdCl2(2,2'-bis(diphenylphosphinomethyl)propionic acid)]
• CAS: 1052093-88-5
• 化学式: C₂₉H₂₈Cl₂O₂P₂Pd
• 分子量: 647.814
• InChiKey: FBZLXWWEBCIZTI-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [PdCl2(2,2'-bis(diphenylphosphinomethyl)propionic acid)] 、 silver trifluoromethanesulfonate 、 乙腈 以 乙腈 为溶剂， 以76%的产率得到[Pd(NCMe)2(2,2'-bis(diphenylphosphinomethyl)propionic acid)][OTf]2
  参考文献：
  名称：

  Coordination chemistry of 2,2-bis(diphenylphosphinomethyl)propionic acid

  摘要：

  The coordination chemistry of the diphosphine ligands 2,2-bis(diphenylphosphinomethyl)propionic acid, 1, and 2,2-bis(diphenylphosphinomethyl) propionate, 2, with copper(I), silver(I), gold(I), palladium(II) and platinum(II) is described. Structure determinations show that the carboxylic acid group in 1 can hydrogen bond to solvent molecules, to anions or to the carboxylic acid group of a neighboring complex, as in the complexes [MCl2(1)] 2DMSO (M = Pd or Pt), [Pt(1)(2)](OTf)(2) or [Pd(NCMe)(2)(1)](OTf)(2), respectively. The tridentate diphosphine-carboxylate ligand 2 forms oligomeric or polymeric complexes, such as [{Ag(2)}(n)], [{PdCl(2)}(n)] or [{PtMe(2)}(n)]. (C) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2007.08.032
• 作为产物：
  描述：

  dichloro(cycloocta-1,5-diene)palladium (II) 、 2,2'-bis(diphenylphosphinomethyl)propionic acid 以 二氯甲烷 为溶剂， 以63%的产率得到[PdCl2(2,2'-bis(diphenylphosphinomethyl)propionic acid)]
  参考文献：
  名称：

  Coordination chemistry of 2,2-bis(diphenylphosphinomethyl)propionic acid

  摘要：

  The coordination chemistry of the diphosphine ligands 2,2-bis(diphenylphosphinomethyl)propionic acid, 1, and 2,2-bis(diphenylphosphinomethyl) propionate, 2, with copper(I), silver(I), gold(I), palladium(II) and platinum(II) is described. Structure determinations show that the carboxylic acid group in 1 can hydrogen bond to solvent molecules, to anions or to the carboxylic acid group of a neighboring complex, as in the complexes [MCl2(1)] 2DMSO (M = Pd or Pt), [Pt(1)(2)](OTf)(2) or [Pd(NCMe)(2)(1)](OTf)(2), respectively. The tridentate diphosphine-carboxylate ligand 2 forms oligomeric or polymeric complexes, such as [{Ag(2)}(n)], [{PdCl(2)}(n)] or [{PtMe(2)}(n)]. (C) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2007.08.032