rhodium(1+)-[(1,2,5,6)-1,5-cyclooctadiene]-[[(1-methylthio-S)-3-[(diphenylphosphino-P)oxy]propyl]benzene]-tetrafluoroborate(1-) | 749850-16-6

• 英文名称: rhodium(1+)-[(1,2,5,6)-1,5-cyclooctadiene]-[[(1-methylthio-S)-3-[(diphenylphosphino-P)oxy]propyl]benzene]-tetrafluoroborate(1-)
• CAS: 749850-16-6
• 化学式: BF₄*C₃₀H₃₅OPRhS
• 分子量: 664.357
• InChiKey: ZENHNVPZNHIVJB-ONEVTFJLSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate 、 [1-methylthio-3-[(diphenylphosphino)oxy]propyl]-benzene 以 二氯甲烷 为溶剂， 以89%的产率得到rhodium(1+)-[(1,2,5,6)-1,5-cyclooctadiene]-[[(1-methylthio-S)-3-[(diphenylphosphino-P)oxy]propyl]benzene]-tetrafluoroborate(1-)
  参考文献：
  名称：

  Rhodium complexes possessing S-phosphinite ligands with or without an amino group: application to hydroformylation of styrene

  摘要：

  A chelate cationic rhodium(I) complex with a hemilabile amino- and sulfur-containing phosphinite ligand has been synthesized and, according to the NMR data, the ligand is bound to the metal in a P. S-bidentate coordination mode without any Rh-N interaction. This complex efficiently catalyzes the hydroformylation of styrene. The chelate rhodiurn complex with the analogous ligand without the amino group has also been synthesized and examined as a catalyst for the same hydroformylation reaction. The reaction rate is higher using the former complex compared to the latter one without the amino group, with, however, a slightly lower regioselectivity towards the formation of the branched aldehyde. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2004.02.005