[2,5-Ph2-3,4-Tol2(η4-C4CO)Ru(CO)2(pyridine)] | 503159-01-1

• 英文名称: [2,5-Ph2-3,4-Tol2(η4-C4CO)Ru(CO)2(pyridine)]
• 英文别名: [2,5-Ph2-3,4-Tol2(η4-C4CO)]Ru(CO)2(pyridine)
• CAS: 503159-01-1
• 化学式: C₃₈H₂₉NO₃Ru
• 分子量: 648.723
• InChiKey: ZPAFCNGAMQKUHK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  吡啶 、 以 吡啶 为溶剂， 生成 [2,5-Ph2-3,4-Tol2(η4-C4CO)Ru(CO)2(pyridine)]
  参考文献：
  名称：

  Synthesis and Reactivity of Hydroxycyclopentadienyl and Aminocyclopentadienyl Ruthenium Alcohol Complexes

  摘要：

  Cationic aminocyclopentadienyl and hydroxycyclopentadienyl ruthenium alcohol complexes were synthesized from reaction of the corresponding ruthenium chloride with AgBF4 in the presence of an alcohol. Exchange rates of free alcohol with hydroxycyclopentadienyl and aminocyclopentadienyl ruthenium benzyl alcohol complexes were rapid (t(1/2) = 5-10 min) at -47 degreesC.

  DOI：

  10.1021/om020891e

文献信息

• A Boron-Substituted Analogue of the Shvo Hydrogenation Catalyst: Catalytic Hydroboration of Aldehydes, Imines, and Ketones
  作者：Liza Koren-Selfridge、Hannah N. Londino、Jessica K. Vellucci、Bryan J. Simmons、Charles P. Casey、Timothy B. Clark

  DOI：10.1021/om801228m

  日期：2009.4.13

  4-Tol2(η5-C4CO)Ru(CO)2]24. Complex 5 reacts with aldehydes both stoichiometrically and catalytically, providing hydroboration products under mild reaction conditions. A Hammett correlation plot of para-substituted benzaldehydes provided a ρ value of +0.91. Catalytic hydroboration of aryl imines provided high yields of the corresponding amines. The hydroboration of aryl ketones, however, required strongly electron-withdrawing

  硼-取代的钌hydroxycycylopentadienyl氢化[2,5-PH 2 -3,4-托尔2（η 5 -C 4 COBPIn）的Ru（CO）2 H]（BPIN = 4,4,5,5-四甲基-1- -1,3,2-二氧硼戊环）5通过加入频哪醇的钌二聚体[2,5-PH合成2 -3,4-托尔2（η 5 -C 4 CO）的Ru（CO）2 ] 2 4。复杂5在化学计量和催化上与醛反应，在温和的反应条件下提供硼氢化产物。对位取代的苯甲醛的Hammett相关图提供了+0.91的ρ值。芳基亚胺的催化加氢硼化提供相应胺的高产率。然而，芳基酮的氢硼化需要强烈的吸电子取代基以在合理的反应时间内诱导氢硼化。