| 565177-86-8

• CAS: 565177-86-8
• 化学式: C₂₃H₂₆Cl₂CoN₂O
• 分子量: 476.371
• InChiKey: IECJZVXUJHCIIM-GJWQCUAUSA-L

反应信息

• 作为产物：
  描述：

  cobalt(II) chloride hexahydrate 、 N-[2,6-di(propan-2-yl)phenyl]-1-[6-(furan-2-yl)pyridin-2-yl]ethanimine 以 正丁醇 为溶剂， 生成
  参考文献：
  名称：

  Selective Oligomerization of Ethylene to Linear α-Olefins by Tetrahedral Cobalt(II) Complexes with 6-(Organyl)-2-(imino)pyridyl Ligands:  Influence of the Heteroatom in the Organyl Group on the Catalytic Activity

  摘要：

  The oligomerization of ethylene to alpha-olefins has been obtained by MAO activation of tetrahedral Co-II complexes of iminopyridines substituted in the 6-position of the pyridine ring by thiophen-2-yl, furan-2-yl, or phenyl groups. An intriguing heteroatom effect has been noticed on both activity and selectivity, together with a change in the Co-II spin state upon activation of the dichloride precursors with MAO.

  DOI：

  10.1021/om030227d