GaCl2(2,6-di(4-tert-butylphenyl)phenyl)*(diethyl ether) | 910626-28-7

• 英文名称: GaCl2(2,6-di(4-tert-butylphenyl)phenyl)*(diethyl ether)
• CAS: 910626-28-7
• 化学式: C₃₀H₃₉Cl₂GaO
• 分子量: 556.268
• InChiKey: RGVMSOMALLGIKB-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  乙醚 、 氯化镓 、 2,6-bis(4-tertbutylphenyl)phenyl lithium 以 乙醚 为溶剂， 以38%的产率得到GaCl2(2,6-di(4-tert-butylphenyl)phenyl)*(diethyl ether)
  参考文献：
  名称：

  2,6-Di(4-t-butylphenyl)phenyl-group 13 organometallic compounds

  摘要：

  Reaction of MX3 (M = Al, Ga, In; X = Br, Q with RLi (R = 2,6-(4-t-BuC6H4)(2)C6H3) affords RGaCl2 - OEt2, 1, (RAlBr2OEt2)-O-., 2, R2GaCl, 3, and R3In, 4. These sterically demanding compounds have been characterized by elemental analyses, H-1 NMR spectroscopy, and single crystal X-ray diffraction. The geometry about the metal centers in I and 2 is best described as distorted tetrahedral while the coordination about the gallium atom in 3 is distorted trigonal planar. Compound 4, with the indium atom in a trigonal planar environment, is noteworthy as the first example of a tris(m-terphenyl) group 13 metal compound. The propeller arrangement of the three ligands in compound 4 serves to virtually encapsulate the metallic center. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2006.05.024