[((tris(2-hydroxybenzylaminoethyl)amine-2H)Ni)CuCl2]*nitromethane | 1310898-48-6

• 英文名称: [((tris(2-hydroxybenzylaminoethyl)amine-2H)Ni)CuCl2]*nitromethane
• CAS: 1310898-48-6
• 化学式: CH₃NO₂*C₂₇H₃₄Cl₂CuN₄NiO₃
• 分子量: 716.774
• InChiKey: MRTMDWZNIOCRRI-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  nickel(II) nitrate hexahydrate 、 硝基甲烷 、 tris(((2-hydroxybenzyl)amino)ethyl)amine 、 copper dichloride 在 NEt₃ 作用下， 以 甲醇 为溶剂， 以68%的产率得到[((tris(2-hydroxybenzylaminoethyl)amine-2H)Ni)CuCl2]*nitromethane
  参考文献：
  名称：

  The use of hydrogenated Schiff base ligands in the synthesis of multi-metallic compounds II

  摘要：

  Tris(2-hydroxybenzylaminoethyl)amine (H3L) complexes of nickel, copper and zinc are investigated as potential metallo-ligands ([(HxL)M]; x = 0, 1: M = Ni, Cu, Zn). The homometallic complexes formed are dimetallic ([{(HL)Ni)Ni(OAc)(2)] and [{(L)Zn}ZnCl]), tetrametallic ([{(L)Cu}Cu](2)(2+)) and hexametallic (R(L)Ni)Ni-2(mu-OH)(2)(OEt)(OH2)](2)). Hetero-dimetallic complexes can be formed with [(HL)Ni] and copper chloride ([{(HL)Ni}CuCl2]) or zinc bromide ([{(HL)Ni}ZnBr2]). The metallo-ligand acts as a chelating agent using phenolate pairs. The remaining phenolate either does not coordinate or can be used to increase the number of metals included in the scaffold from two to four or six. Not all combinations are possible and [(HL)Cur produces a charge separated species with zinc chloride rather than a complex. An exchange reaction is observed to take place when [(HL)Zn+ is treated with the halides of nickel or copper producing [(HL)M+ (M = Ni, Cu, respectively). (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2011.03.004