[PdCl2(N,N,N'-trimethyl-N'-cetylethylenediamine)] | 1401464-77-4

• 英文名称: [PdCl2(N,N,N'-trimethyl-N'-cetylethylenediamine)]
• 英文别名: [PdCl2(C16-tmen)]
• CAS: 1401464-77-4
• 化学式: C₂₁H₄₆Cl₂N₂Pd
• 分子量: 503.936
• InChiKey: CFAFNUQTGQTADQ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  双(乙腈)氯化钯(II) 、 N,N,N'-Trimethyl-N'-hexadecylethylene diamine 以 二氯甲烷 为溶剂， 以45.9%的产率得到[PdCl2(N,N,N'-trimethyl-N'-cetylethylenediamine)]
  参考文献：
  名称：

  Preparation of palladium(II) complexes with long alkyl chain ligand incorporated in micelle

  摘要：

  Three palladium(II) complexes with a bidentate nitrogen ligand having a long alkyl chain (1, [PdCl2(C-8-tmen)], C-8-tmen = N,N,N'-trimethyl-N'-octylethylenediamine; 2, [PdCl2(C-16-tmen)], C-16-tmen = N,N,N'-trimethyl-N'-cetylethylenediamine; 3, [PdCl2(C-8-bpy)], C-8-bpy = 4-octyl-2,2'-bipyridine) were prepared. Addition of 1 to an aqueous solution of cetyltrimethylammonium bromide gave a metallomicelle containing the Pd(II) complex (1A). The other palladium complexes (2 and 3) were not incorporated into the CTABr micelle due to the unsuitable matching between the ligand and the micelle. 1A showed good catalytic performance for Suzuki and Heck coupling reactions in water. The catalyst system for the Heck reaction in water was reusable. (C) 2012 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2012.05.015