[PdCl₂(1,1’-bis(diphenylarsino)ferrocene)] | 32611-11-3

• 英文名称: [PdCl₂(1,1’-bis(diphenylarsino)ferrocene)]
• 英文别名: [PdCl₂(dpaf)]；dichloro-bis(1,1'-bis(diphenylarsino)ferrocene)-palladium
• CAS: 32611-11-3
• 化学式: C₃₄H₂₈As₂Cl₂FePd
• 分子量: 819.613
• InChiKey: PPUDKVNRPOVQMW-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  1,1’-bis(diphenylarsino)ferrocene 、 双(乙腈)氯化钯(II) 以 二氯甲烷 为溶剂， 反应 2.0h， 以40%的产率得到[PdCl₂(1,1’-bis(diphenylarsino)ferrocene)]
  参考文献：
  名称：

  Compounds containing weak, non-covalent interactions to the metal in the backbone of 1,1′-bis(phosphino)metallocene ligands

  摘要：

  The reactions of Na[BArF] (BArF = tetrakis(3,5-bis(trifluoromethyl)phenyl)borate) with a series of [Pd(dpEMc)Cl-2] (dpEMc = 1,1'-bis(diphenylphosphino)ruthenocene (dppr), 1,1'-bis(diphenylphosphino)osmocene (dppo) or 1,1'-bis(diphenylarsino)ferrocene (dpaf)) compounds were examined. The reaction of Na[BArF] with [Pd(dppMc)Cl-2] (dppMc = dppr or dppo) resulted in the formation of the corresponding chloride-bridged dimers, [Pd(dppMc)(mu-Cl)](2)(2+), which were structurally characterized. However, these dimers appear to be unstable in CH2Cl2 and partially (Ru) or fully (Os) convert into the corresponding monomers, [Pd(dppMc)Cl](+), which are proposed to have a weak, non-covalent M-Pd (M = Ru or Os) interaction. Similar compounds, [Pd(dppo)PPh3](2+) and [Pt(dppMc)PPh3](2+) (M = Fe (1,1'-bis(diphenylphosphino)ferrocene (dppf)) or Os (dppo)), were also prepared and structurally characterized. These compound also exhibit weak, non-covalent M-Pd/Pt interactions. In addition, the electrochemical properties of these compounds were examined by cyclic voltammetry. (C) 2015 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2015.11.025

文献信息

• Construction of a Bidentate Arsenic Ligand Library Starting from a Cyclooligoarsine
  作者：Hiroaki Imoto、Masafumi Konishi、Shintaro Nishiyama、Hiroshi Sasaki、Susumu Tanaka、Takashi Yumura、Kensuke Naka

  DOI：10.1246/cl.190540

  日期：2019.11.5

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