| 600698-63-3

• CAS: 600698-63-3
• 化学式: C₁₄H₁₇BClN₇O₂Ru
• 分子量: 462.669
• InChiKey: LMDWJFKDXLVWDP-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  (hydridotris(pyrazol-1-yl)borate)nitrosylruthenium(CCC(Me)2OH)Cl 、 水 在 HBF₄*(CH₃CH₂)2O 作用下， 以 甲醇 为溶剂， 以31%的产率得到
  参考文献：
  名称：

  Hydration of Nitrosylruthenium Acetylide Complexes Having a Tris(pyrazol-1-yl)borate in the Presence of Protic Acid:  Formation of Ketonyl and Acyl Complexes

  摘要：

  Treatment of the monoacetylide complexes TpRuCl(CdropCR)(NO) (R = Ph (1a), p-CH3C6H4 (1b), Bu-t (1c), CH2CH2OH (Id), CH2OH (1e), C(Me)(2)OH (1f), C(Ph)(2)OH (1g); Tp = BH(pyrazol-1-yl)(3)) with HBF4.Et2O in methanol afforded the ketonyl complexes TpRuCl-(CH2C(O)R)(NO) (R = Ph (2a), p-CH3C6H4 (2b), Bu-t (2c), CH2CH2OMe (2d), CH2OH (2e)) and the alpha,beta-unsaturated acyl complexes TpRuCl(C(O)CH=CR'(2))(NO) (R' = Me (3f), Ph (3g)), respectively. While the latter were produced by hydration via allenylidene species, the former were presumably generated from the reaction of eta(2)-coordinated 1-alkyne species with adventitious water.

  DOI：

  10.1021/om0303597